Chalcogen controlled redox behaviour in peri-substituted S, Se and Te naphthalene derivatives

Tracey L. Roemmele; Fergus R. Knight; Ellis Crawford; Stuart D. Robertson; Bela E. Bode; Michael Bühl; Alexandra M. Z. Slawin; J. Derek Woollins; René T. Boeré

doi:10.1039/d2nj04737c

journal article Jan 01, 2022

Chalcogen controlled redox behaviour in peri-substituted S, Se and Te naphthalene derivatives

Tracey L. Roemmele Fergus R. Knight Ellis Crawford

Stuart D. Robertson

Bela E. Bode

Michael Bühl

Alexandra M. Z. Slawin

J. Derek Woollins René T. Boeré

New Journal of Chemistry Vol. 46 No. 46 pp. 22363-22383 · Royal Society of Chemistry (RSC)

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Abstract

Chemically reversible electron transfers between neutral, cation radical and dication naphthalenic peri-1,8-diphenylchalcogenides are governed by chalcogen (SS, SSe, STe, SeSe, SeTe, TeTe) contributions to the redox molecular orbitals.

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Details

Published: Jan 01, 2022
Vol/Issue: 46(46)
Pages: 22363-22383
License: View

Authors

T

Tracey L. Roemmele

Dept of Chemistry and Biochemistry and Canadian Centre for Research in Advanced Fluorine Technologies, University of Lethbridge, Lethbridge, AB, T1K 3M4, Canada

F

Fergus R. Knight