Mechanistic insight into anti-carbometalation of an alkyne via η2-vinyl-nickel type Z/E isomerization

Chunhui Shan; Miaomiao He; Xiaoling Luo; Rong Li; Tao Zhang

doi:10.1039/d3qo00723e

journal article Jan 01, 2023

Mechanistic insight into anti-carbometalation of an alkyne via η2-vinyl-nickel type Z/E isomerization

Chunhui Shan

Miaomiao He Xiaoling Luo

Rong Li

Tao Zhang

Organic Chemistry Frontiers Vol. 10 No. 17 pp. 4243-4249 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d3qo00723e

Abstract

In this reaction, η2-vinyl-nickel type Z/E isomerization is found to be lower in energy compared with carbonyl-assisted Z/E isomerization from a syn-alkenylnickel intermediate.

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Details

Published: Jan 01, 2023
Vol/Issue: 10(17)
Pages: 4243-4249
License: View

Authors

C

Chunhui Shan

Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, China

M

Miaomiao He

Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, China

X

Xiaoling Luo

Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, China

R

Rong Li

Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, China

T

Tao Zhang

ZhengZhou JiShu Institute of AI Science, Zhengzhou, Henan 450000, China

Funding

National Natural Science Foundation of China Award: 22103008

China Postdoctoral Science Foundation Award: 2022M710548

Chongqing Municipal Education Commission Award: KJQN202000541

Chongqing Normal University Award: 21XLB013

Cite This Article

Chunhui Shan, Miaomiao He, Xiaoling Luo, et al. (2023). Mechanistic insight into anti-carbometalation of an alkyne via η2-vinyl-nickel type Z/E isomerization. Organic Chemistry Frontiers, 10(17), 4243-4249. https://doi.org/10.1039/d3qo00723e

Mechanistic insight into anti-carbometalation of an alkyne via η2-vinyl-nickel type Z/E isomerization

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