Quenching-induced lattice modifications endowing Li-rich layered cathodes with ultralow voltage decay and long life

Lingcai Zeng; Haoyan Liang; Yaqian Wang; Xiaolong Ying; Bao Qiu; Jiajie Pan; Yibin Zhang; Wen Wen; Xuechun Wang; Qingwen Gu; Junhao Li; Kaixiang Shi; Yanbin Shen; Quanbing Liu

doi:10.1039/d4ee02511c

journal article Jan 01, 2025

Quenching-induced lattice modifications endowing Li-rich layered cathodes with ultralow voltage decay and long life

Lingcai Zeng Haoyan Liang Yaqian Wang Xiaolong Ying Bao Qiu

Jiajie Pan Yibin Zhang

Qingwen Gu Junhao Li

Energy Environ. Sci. Vol. 18 No. 1 pp. 284-299 · Royal Society of Chemistry (RSC)

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Abstract

A versatile brine-quenching strategy implements a combined surface-bulk-compatible structure design to modulate the intrinsic redox properties of Li-rich layered oxides, ultimately achieving ultra-long lifetimes and negligible voltage decay.

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Details

Published: Jan 01, 2025
Vol/Issue: 18(1)
Pages: 284-299
License: View

Authors

L

Lingcai Zeng

Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China; Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

H

Haoyan Liang

Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China

Y

Yaqian Wang

Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China

X

Xiaolong Ying

Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China

B

Bao Qiu

Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

J

Jiajie Pan

Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Y

Yibin Zhang

Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China

W

Wen Wen

Shanghai Synchrotron Radiation Facility, Chinese Academy of Sciences, Zhangjiang High-Tech. Park, Pudong New Area, Shanghai, China

X

Xuechun Wang

i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences, Suzhou 215123, China

Q

Qingwen Gu

Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China

J

Junhao Li

Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

K

Kaixiang Shi

Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Y

Yanbin Shen

i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences, Suzhou 215123, China

Q

Quanbing Liu

Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Funding

National Natural Science Foundation of China Award: 52272253

Chinese Academy of Sciences Award: 181GJHZ2024126MI

Youth Innovation Promotion Association of the Chinese Academy of Sciences Award: 2022299

Natural Science Foundation of Zhejiang Province Award: LQ22B030013

National Key Research and Development Program of China Award: 2021YFB3803002

Key Research and Development Program of Zhejiang Province Award: 2022C01071

Natural Science Foundation of Ningbo Municipality Award: 2024QL041

Cite This Article

Lingcai Zeng, Haoyan Liang, Yaqian Wang, et al. (2025). Quenching-induced lattice modifications endowing Li-rich layered cathodes with ultralow voltage decay and long life. Energy Environ. Sci., 18(1), 284-299. https://doi.org/10.1039/d4ee02511c

Quenching-induced lattice modifications endowing Li-rich layered cathodes with ultralow voltage decay and long life

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