journal article Open Access Jan 01, 2025

Ultra-high molecular weight polymer synthesis via aqueous dispersion polymerization

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Abstract
Polymerization-induced self-assembly (PISA) is leveraged for the synthesis of ultra-high molecular weight polymers in concentrated but free-flowing dispersions.
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References
50
[1]
Streicher ACS Appl. Mater. Interfaces (2023) 10.1021/acsami.3c14483
[2]
Kamiyama Sci. Adv. (2022) 10.1126/sciadv.add0226
[3]
Mapas Macromolecules (2016) 10.1021/acs.macromol.6b00863
[4]
Kamiyama Soft Matter (2022) 10.1039/d2sm00853j
[5]
Ultra-High Molecular Weights via Aqueous Reversible-Deactivation Radical Polymerization

R. Nicholas Carmean, Troy E. Becker, Michael B. Sims et al.

Chem 2017 10.1016/j.chempr.2016.12.007
[6]
Ultrahigh Molecular Weight Hydrophobic Acrylic and Styrenic Polymers through Organic-Phase Photoiniferter-Mediated Polymerization

R. Nicholas Carmean, Michael B. Sims, C. Adrian Figg et al.

ACS Macro Letters 2020 10.1021/acsmacrolett.0c00203
[7]
Rzayev Angew. Chem., Int. Ed. (2004) 10.1002/anie.200353025
[8]
Simms Macromolecules (2007) 10.1021/ma061899t
[9]
Mueller Eur. Polym. J. (2011) 10.1016/j.eurpolymj.2010.10.006
[10]
Zhang Polymers (2023) 10.3390/polym15112501
[11]
Yuan Polymers (2020) 10.3390/polym12112747
[12]
De J. Polym. Sci., Part A:Polym. Chem. (2013) 10.1002/pola.26520
[13]
Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C

Virgil Percec, Tamaz Guliashvili, Janine S. Ladislaw et al.

Journal of the American Chemical Society 2006 10.1021/ja065484z
[14]
Reyhani J. Polym. Sci., Part A: Polym. Chem. (2019) 10.1002/pola.29318
[15]
An Atom‐Economic Enzymatic Cascade Catalysis for High‐Throughput RAFT Synthesis of Ultrahigh Molecular Weight Polymers

Ruoyu Li, Shudi Zhang, Quanshun Li et al.

Angewandte Chemie International Edition 2022 10.1002/anie.202213396
[16]
Chou Macromolecules (2024) 10.1021/acs.macromol.4c01519
[18]
Photocontrolled RAFT polymerization: past, present, and future

Yungyeong Lee, Cyrille Boyer, Min Sang Kwon

Chemical Society Reviews 2023 10.1039/d1cs00069a
[19]
Li Angew. Chem., Int. Ed. (2020) 10.1002/anie.202010722
[20]
Stacy ACS Macro Lett. (2024) 10.1021/acsmacrolett.4c00642
[21]
Photoiniferter polymerization: Illuminating the history, ascendency, and renaissance

Rhys W. Hughes, Megan E. Lott, Rebecca A. Olson S et al.

Progress in Polymer Science 2024 10.1016/j.progpolymsci.2024.101871
[22]
Young Angew. Chem., Int. Ed. (2024) 10.1002/anie.202408592
[23]
Trachsel J. Am. Chem. Soc. (2024) 10.1021/jacs.4c04664
[24]
Diversification of Acrylamide Polymers via Direct Transamidation of Unactivated Tertiary Amides

Lucca Trachsel, Debabrata Konar, Jason D. Hillman et al.

Journal of the American Chemical Society 2024 10.1021/jacs.3c12174
[25]
Hughes J. Am. Chem. Soc. (2024) 10.1021/jacs.3c14179
[26]
Diodati ACS Appl. Polym. Mater. (2023) 10.1021/acsapm.3c02191
[27]
Lehnen Polym. Chem. (2022) 10.1039/d1py01530c
[28]
Olson Macromolecules (2022) 10.1021/acs.macromol.2c01239
[29]
Davidson ACS Macro Lett. (2023) 10.1021/acsmacrolett.3c00431
[30]
Lott Macromolecules (2024) 10.1021/acs.macromol.4c00366
[31]
Rucco Biomacromolecules (2020) 10.1021/acs.biomac.0c01225
[32]
Korpusik Macromolecules (2021) 10.1021/acs.macromol.1c01276
[33]
Rho Polym. Chem. (2021) 10.1039/d1py00239b
[34]
Penfold ACS Macro Lett. (2024) 10.1021/acsmacrolett.9b00464
[35]
Wang Polym. Chem. (2024)
[36]
Warren J. Am. Chem. Soc. (2014) 10.1021/ja502843f
[37]
Wong Polym. Chem. (2025) 10.1039/d4py01323a
[38]
Figg Chem. Sci. (2015) 10.1039/c4sc03334e
[39]
Ratcliffe Angew. Chem., Int. Ed. (2019) 10.1002/anie.201909124
[40]
Canning Macromolecules (2016) 10.1021/acs.macromol.5b02602
[41]
McBride Macromolecules (2022) 10.1021/acs.macromol.2c01071
[42]
McBride Macromolecules (2024) 10.1021/acs.macromol.3c02616
[43]
Cunningham Macromolecules (2016) 10.1021/acs.macromol.6b00820
[44]
György Macromolecules (2024) 10.1021/acs.macromol.4c01078
[45]
Scheutz ACS Macro Lett. (2023) 10.1021/acsmacrolett.3c00148
[46]
Hughes ACS Macro Lett. (2023) 10.1021/acsmacrolett.2c00683
[47]
Blanazs J. Am. Chem. Soc. (2011) 10.1021/ja206301a
[48]
Couturaud Macromol. Rapid Commun. (2019) 10.1002/marc.201800460
[49]
Bowman Angew. Chem., Int. Ed. (2023) 10.1002/anie.202309951
[50]
Polymer Physics

Michael Rubinstein, Ralph H Colby

2003 10.1093/oso/9780198520597.001.0001
Metrics
16
Citations
50
References
Details
Published
Jan 01, 2025
Vol/Issue
16(13)
Pages
5573-5578
License
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Authors
Funding
Division of Materials Research Award: DMR-2404144
Army Research Office Award: W911NF2310260
National Defense Science and Engineering Graduate
Cite This Article
Cabell B. Eades, Kaden C. Stevens, Danyella E. Cabrera, et al. (2025). Ultra-high molecular weight polymer synthesis via aqueous dispersion polymerization. Chemical Science, 16(13), 5573-5578. https://doi.org/10.1039/d5sc00589b
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