Dual-anion regulation engineering enhances chloridion corrosion resistance for long-lasting industrial-scale seawater splitting

Tianqi GAO; Wenzhe Wang; Zenong Zhang; Wanyu Li; Huanhuan Gao; Jiawei Liu; Xiaojun Zhao; Zhi‐Hong Liu; Yu Chen

doi:10.1039/d5sc03775a

journal article Open Access Jan 01, 2025

Dual-anion regulation engineering enhances chloridion corrosion resistance for long-lasting industrial-scale seawater splitting

Tianqi GAO

Wenzhe Wang

Zenong Zhang Wanyu Li Huanhuan Gao Jiawei Liu

Xiaojun Zhao

Zhi‐Hong Liu

Yu Chen

Chemical Science Vol. 16 No. 34 pp. 15684-15696 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d5sc03775a

Abstract

The B4O5(OH)42−–CoFe-LDH/SO42−–CoMoO4 nanohybrid, with an amorphous/crystalline interface, enables efficient seawater splitting. Its dual B4O5(OH)42−/SO42− layers suppress Cl− corrosion, facilitating stable industrial-scale seawater splitting.

Topics

No keywords indexed for this article. Browse by subject →

References

68

[1]

Water-hydroxide trapping in cobalt tungstate for proton exchange membrane water electrolysis

Ranit Ram, Lu Xia, Hind Benzidi et al.

Science 2024 10.1126/science.adk9849

[2]

Future environmental impacts of global hydrogen production

Shijie Wei, Romain Sacchi, Arnold Tukker et al.

Energy Environ. Sci. 2024 10.1039/d3ee03875k

[3]

Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation

Jianxin Kang, Xiaoyi Qiu, Qi Hu et al.

Nature Catalysis 2021 10.1038/s41929-021-00715-w

[4]

Fan Nat. Sustain. (2024) 10.1038/s41893-023-01263-w

[5]

Du Adv. Funct. Mater. (2024) 10.1002/adfm.202407586

[6]

A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer

Xin Kang, Fengning Yang, Heming Liu et al.

Nature Communications 2023 10.1038/s41467-023-39386-5

[7]

Shen Energy Environ. Sci. (2024) 10.1039/d4ee00950a

[8]

Liao Adv. Mater. (2024) 10.1002/adma.202405852

[9]

Yu ACS Catal. (2024) 10.1021/acscatal.4c05704

[10]

Xu Adv. Mater. (2024) 10.1002/adma.202306062

[11]

Abdelhafiz Adv. Energy Mater. (2024) 10.1002/aenm.202303350

[12]

Wu Adv. Funct. Mater. (2020) 10.1002/adfm.201910274

[13]

Dionigi Angew. Chem., Int. Ed. (2021) 10.1002/anie.202100631

[14]

Dual Cocatalytic Sites Synergize NiFe Layered Double Hydroxide to Boost Oxygen Evolution Reaction in Anion Exchange Membrane Water Electrolyzer

Yue Shi, Lumin Song, Yan Liu et al.

Advanced Energy Materials 2024 10.1002/aenm.202402046

[15]

Song Appl. Catal., B (2024) 10.1016/j.apcatb.2024.124028

[16]

Gao J. Energy Chem. (2025) 10.1016/j.jechem.2024.11.072

[17]

Liu Chem. Sci. (2024) 10.1039/d4sc05799f

[18]

Zhou Appl. Catal., B (2023) 10.1016/j.apcatb.2023.122749

[19]

Chen Coord. Chem. Rev. (2024) 10.1016/j.ccr.2024.215832

[20]

Deng Adv. Energy Mater. (2024) 10.1002/aenm.202400053

[21]

Wang Small (2024) 10.1002/smll.202311431

[22]

Mu ACS Energy Lett. (2024) 10.1021/acsenergylett.4c02552

[23]

Li Chem. Eng. J. (2025) 10.1016/j.cej.2025.159290

[24]

Zeng Energy Storage Mater. (2023) 10.1016/j.ensm.2023.102806

[25]

Hu Adv. Energy Mater. (2021) 10.1002/aenm.202002816

[26]

Wang Adv. Energy Mater. (2025) 10.1002/aenm.202402883

[27]

Zhang ACS Nano (2024) 10.1021/acsnano.3c12049

[28]

Synergistic Activation of Crystalline Ni2P and Amorphous NiMoOx for Efficient Water Splitting at High Current Densities

Jin-Tao Ren, Lei Chen, Wen-Wen Tian et al.

ACS Catalysis 2023 10.1021/acscatal.3c01885

[29]

He Chem. Sci. (2024) 10.1039/d3sc05220f

[30]

Fu Chem. Eng. J. (2025) 10.1016/j.cej.2025.159520

[31]

Fe2O3/P-doped CoMoO4 electrocatalyst delivers efficient overall water splitting in alkaline media

Bowen Wang, Xiangxiong Chen, Yingjian He et al.

Applied Catalysis B: Environmental 2024 10.1016/j.apcatb.2024.123741

[32]

Fei Chem. Eng. J. (2020) 10.1016/j.cej.2020.124926

[33]

Hao ACS Energy Lett. (2023) 10.1021/acsenergylett.3c01747

[34]

Nguyen Adv. Funct. Mater. (2021) 10.1002/adfm.202106229

[35]

Zhu Sci. Bull. (2024) 10.1016/j.scib.2023.12.025

[36]

Li Green Chem. (2023) 10.1039/d3gc03210h

[37]

Du J. Energy Chem. (2024) 10.1016/j.jechem.2024.01.028

[38]

Zhang Chin. J. Struct. Chem. (2024)

[39]

Zhao Sci. Bull. (2023) 10.1016/j.scib.2023.06.001

[40]

Guo Carbon Energy (2024) 10.1002/cey2.532

[41]

Guo Chin. J. Struct. Chem. (2024)

[42]

Progress in Anode Stability Improvement for Seawater Electrolysis to Produce Hydrogen

Sixie Zhang, Wenwen Xu, Haocheng Chen et al.

Advanced Materials 2024 10.1002/adma.202311322

[43]

Hu Chem. Eng. J. (2016) 10.1016/j.cej.2016.02.095

[44]

Jun Spectrochim. Acta, Part A (1995) 10.1016/0584-8539(94)00183-c

[45]

Tian J. Mater. Chem. A (2024) 10.1039/d4ta02740j

[46]

Yu Nano Energy (2019) 10.1016/j.nanoen.2019.103880

[47]

Cai Carbon Energy (2024) 10.1002/cey2.543

[48]

Shi ACS Catal. (2022) 10.1021/acscatal.2c02586

[49]

Tan Energy Environ. Sci. (2025) 10.1039/d4ee05379f

[50]

Design Criteria, Operating Conditions, and Nickel–Iron Hydroxide Catalyst Materials for Selective Seawater Electrolysis

Fabio Dionigi, Tobias Reier, Zarina Pawolek et al.

ChemSusChem 2016 10.1002/cssc.201501581

Showing 50 of 68 references

Metrics

13

Citations

68

References

Details

Published: Jan 01, 2025
Vol/Issue: 16(34)
Pages: 15684-15696
License: View

Authors

T

Tianqi GAO

Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

W

Wenzhe Wang

Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

Z

Zenong Zhang

Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

W

Wanyu Li

Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

H

Huanhuan Gao

Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

J

Jiawei Liu

Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong 999077, P. R. China

X

Xiaojun Zhao

School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, P. R. China

Z

Zhi‐Hong Liu

Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

Y

Yu Chen

School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710119, P. R. China

Funding

National Natural Science Foundation of China Award: 22073061

Fundamental Research Funds for the Central Universities Award: GK202505036

Shaanxi Key Science and Technology Innovation Team Project Award: 2023-CX-TD-27

Cite This Article

Tianqi GAO, Wenzhe Wang, Zenong Zhang, et al. (2025). Dual-anion regulation engineering enhances chloridion corrosion resistance for long-lasting industrial-scale seawater splitting. Chemical Science, 16(34), 15684-15696. https://doi.org/10.1039/d5sc03775a

Dual-anion regulation engineering enhances chloridion corrosion resistance for long-lasting industrial-scale seawater splitting

You May Also Like