Ion-induced nucleation: A density functional approach

I. Kusaka; Z.-G. Wang; J. H. Seinfeld

doi:10.1063/1.469158

journal article Jan 08, 1995

Ion-induced nucleation: A density functional approach

I. Kusaka Z.-G. Wang J. H. Seinfeld

The Journal of Chemical Physics Vol. 102 No. 2 pp. 913-924 · AIP Publishing

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Abstract

Density functional theory is applied to ion-induced nucleation of dipolar molecules. The predicted reversible work shows a sign preference, resulting in a difference in the nucleation rate by a factor of 10–102, for realistic values of model parameters. The sign effect is found to decrease systematically as the supersaturation is increased. The asymmetry of a molecule is shown to be directly responsible for the sign preference in ion-induced nucleation.

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Binary nucleation of sulfuric acid-water: Monte Carlo simulation

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Citations

27

References

Details

Published: Jan 08, 1995
Vol/Issue: 102(2)
Pages: 913-924

Authors

I

I. Kusaka

Department of Chemical Engineering, California Institute of Technology, Pasadena, California 91125

Z

Z.-G. Wang

Department of Chemical Engineering, California Institute of Technology, Pasadena, California 91125

J

J. H. Seinfeld

Department of Chemical Engineering, California Institute of Technology, Pasadena, California 91125

Cite This Article

I. Kusaka, Z.-G. Wang, J. H. Seinfeld (1995). Ion-induced nucleation: A density functional approach. The Journal of Chemical Physics, 102(2), 913-924. https://doi.org/10.1063/1.469158

Ion-induced nucleation: A density functional approach

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