Optimised Syntheses of the Half-Sandwich Complexes FeCl(dppe)Cp*, FeCl(dppe)Cp, RuCl(dppe)Cp*, and RuCl(dppe)Cp

Josef B. G. Gluyas; Neil J. Brown; Julian D. Farmer; Paul J. Low

doi:10.1071/ch16322

journal article Jul 28, 2016

Optimised Syntheses of the Half-Sandwich Complexes FeCl(dppe)Cp, FeCl(dppe)Cp, RuCl(dppe)Cp, and RuCl(dppe)Cp

Josef B. G. Gluyas Neil J. Brown Julian D. Farmer Paul J. Low

Australian Journal of Chemistry Vol. 70 No. 1 pp. 113-119 · CSIRO Publishing

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Abstract

Thanks to their synthetic versatility, the half-sandwich metal chlorides MCl(dppe)(?5-C5R5) [M = Fe, Ru; dppe = 1,2-bis(diphenylphosphino)ethane, R = H (cyclopentadiene, Cp), CH3 (pentamethylcyclopentadiene, Cp*)] are staple starting materials in many organometallic laboratories. Here we present an overview of the synthetic methods currently available for FeCl(dppe)Cp*, FeCl(dppe)Cp, RuCl(dppe)Cp*, and RuCl(dppe)Cp, and describe in detail updated and optimised multigram syntheses of all four compounds.

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Details

Published: Jul 28, 2016
Vol/Issue: 70(1)
Pages: 113-119
License: View

Authors

J

Josef B. G. Gluyas

ASchool of Chemistry and Biochemistry, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009, Australia.

N

Neil J. Brown

BDepartment of Chemistry, Durham University, South Road, Durham DH1 3LE, UK.

J

Julian D. Farmer

BDepartment of Chemistry, Durham University, South Road, Durham DH1 3LE, UK.

P

Paul J. Low

ASchool of Chemistry and Biochemistry, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009, Australia.; CCorresponding author. Email: paul.low@uwa.edu.au

Cite This Article

Josef B. G. Gluyas, Neil J. Brown, Julian D. Farmer, et al. (2016). Optimised Syntheses of the Half-Sandwich Complexes FeCl(dppe)Cp*, FeCl(dppe)Cp, RuCl(dppe)Cp*, and RuCl(dppe)Cp. Australian Journal of Chemistry, 70(1), 113-119. https://doi.org/10.1071/ch16322

Optimised Syntheses of the Half-Sandwich Complexes FeCl(dppe)Cp*, FeCl(dppe)Cp, RuCl(dppe)Cp*, and RuCl(dppe)Cp

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