Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery

B. Wu, S. Wang, J. Lochala, D. Desrochers, B. Liu, W. Zhang, J. Yang, J. Xiao, The role of the solid electrolyte interphase layer in preventing Li dendrite growth in solid-state batteries. Energy Environ. Sci. 11, 1803–1810 (2018). 10.1039/c8ee00540k

[6]

10.1149/1.1850854

[7]

J. Wolfenstine, J. L. Allen, J. Sakamoto, D. J. Siegel, H. Choe, Mechanical behavior of Li-ion-conducting crystalline oxide-based solid electrolytes: A brief review. Ionics 24, 1271–1276 (2018). 10.1007/s11581-017-2314-4

[8]

10.1016/s0378-7753(98)00242-0

[9]

Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes

Lukas Porz, Tushar Swamy, Brian W. Sheldon et al.

Advanced Energy Materials 10.1002/aenm.201701003

[10]

R. Garcia-Mendez, F. Mizuno, R. Zhang, T. S. Arthur, J. Sakamoto, Effect of processing conditions of 75Li2S-25P2S5 solid electrolyte on its DC electrochemical behavior. Electrochim. Acta 237, 144–151 (2017). 10.1016/j.electacta.2017.03.200

[11]

M. Nagao, A. Hayashi, M. Tatsumisago, T. Kanetsuku, T. Tsuda, S. Kuwabata, In situ SEM study of a lithium deposition and dissolution mechanism in a bulk-type solid-state cell with a Li2S–P2S5 solid electrolyte. Phys. Chem. Chem. Phys. 15, 18600–18606 (2013). 10.1039/c3cp51059j

[12]

10.1002/aenm.201703644

[13]

10.1016/j.electacta.2016.12.018

[14]

10.1016/j.jpowsour.2017.04.026

[15]

F. Yonemoto, A. Nishimura, M. Motoyama, N. Tsuchimine, S. Kobayashi, Y. Iriyama, Temperature effects on cycling stability of Li plating/stripping on Ta-doped Li7La3Zr2O12. J. Power Sources 343, 207–215 (2017). 10.1016/j.jpowsour.2017.01.009

[16]

R. H. Basappa, T. Ito, T. Morimura, R. Bekarevich, K. Mitsuishi, H. Yamada, Grain boundary modification to suppress lithium penetration through garnet-type solid electrolyte. J. Power Sources 363, 145–152 (2017). 10.1016/j.jpowsour.2017.07.088

[17]

L. L. Baranowski, C. M. Heveran, V. L. Ferguson, C. R. Stoldt, Multi-scale mechanical behavior of the Li3PS4 solid-phase electrolyte. ACS Appl. Mater. Interfaces 8, 29573–29579 (2016). 10.1021/acsami.6b06612

[18]

10.1038/ncomms7362

[19]

10.1016/j.chempr.2017.10.017

[20]

10.1039/c6ee01674j

[21]

10.1002/aenm.201501590

[22]

10.1021/acsami.5b07517

[23]

10.1039/c7cp05253g

[24]

J. Wolfenstine, J. L. Allen, J. Read, J. Sakamoto, Chemical stability of cubic Li7La3Zr2O12 with molten lithium at elevated temperature. J. Mater. Sci. 48, 5846–5851 (2013). 10.1007/s10853-013-7380-z

[25]

N. J. Taylor, S. Stangeland-Molo, C. G. Haslam, A. Sharafi, T. Thompson, M. Wang, R. Garcia-Mendez, J. Sakamoto, Demonstration of high current densities and extended cycling in the garnet Li7La3Zr2O12 solid electrolyte. J. Power Sources 396, 314–318 (2018). 10.1016/j.jpowsour.2018.06.055

[26]

X. Fan, L. Chen, O. Borodin, X. Ji, J. Chen, S. Hou, T. Deng, J. Zheng, C. Yang, S.-C. Liou, K. Amine, K. Xu, C. Wang, Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries. Nat. Nanotechnol. 13, 715–722 (2018). 10.1038/s41565-018-0183-2

[27]

X.-B. Cheng, J.-Q. Huang, Q. Zhang, Review–Li metal anode in working lithium-sulfur batteries. J. Electrochem. Soc. 165, A6058–A6072 (2018). 10.1149/2.0111801jes

[28]

S. Choudhury, L. A. Archer, Lithium fluoride additives for stable cycling of lithium batteries at high current densities. Adv. Electron. Mater. 2, 1500246 (2016). 10.1002/aelm.201500246

[29]

10.1126/sciadv.1602809

[30]

S. P. Ong, L. Wang, B. Kang, G. Ceder, Li–Fe–P–O2 phase diagram from first principles calculations. Chem. Mater. 20, 1798–1807 (2008). 10.1021/cm702327g

[31]

A. Kato, H. Kowada, M. Deguchi, C. Hotehama, A. Hayashi, M. Tatsumisago, XPS and SEM analysis between Li/Li3PS4 interface with Au thin film for all-solid-state lithium batteries. Solid State Ion. 322, 1–4 (2018). 10.1016/j.ssi.2018.04.011

[32]

Interface Stability in Solid-State Batteries

William D. Richards, Lincoln J. Miara, Yan Wang et al.

Chemistry of Materials 10.1021/acs.chemmater.5b04082

[33]

10.1063/1.1744540

[34]

N. D. Lepley, N. A. W. Holzwarth, Modeling interfaces between solids: Application to Li battery materials. Phys. Rev. B 92, 214201 (2015). 10.1103/physrevb.92.214201

[35]

S. Sicolo, M. Fingerle, R. Hausbrand, K. Albe, Interfacial instability of amorphous LiPON against lithium: A combined density functional theory and spectroscopic study. J. Power Sources 354, 124–133 (2017). 10.1016/j.jpowsour.2017.04.005

[36]

J. Yue, F. Han, X. Fan, X. Zhu, Z. Ma, J. Yang, C. Wang, High-performance all-inorganic solid-state sodium–sulfur battery. ACS Nano 11, 4885–4891 (2017). 10.1021/acsnano.7b01445

[37]

10.1021/acsami.6b13925

[38]

W. Sun, M. Xie, X. Shi, L. Zhang, Study of new phases grown on LiNbO3 coated LiCoO2 cathode material with an enhanced electrochemical performance. Mater. Res. Bull. 61, 287–291 (2015). 10.1016/j.materresbull.2014.10.044

[39]

Inhomogeneous Electron Gas

P. Hohenberg, W. Kohn

Physical Review 10.1103/physrev.136.b864

[40]

Self-Consistent Equations Including Exchange and Correlation Effects

W. Kohn, L. J. Sham

Physical Review 10.1103/physrev.140.a1133

[41]

Projector augmented-wave method

P. E. Blöchl

Physical Review B 10.1103/physrevb.50.17953

[42]

Generalized Gradient Approximation Made Simple

John P. Perdew, Kieron Burke, Matthias Ernzerhof

Physical Review Letters 10.1103/physrevlett.77.3865

[43]

Visualization and analysis of atomistic simulation data with OVITO–the Open Visualization Tool

Alexander Stukowski

Modelling and Simulation in Materials Science and... 10.1088/0965-0393/18/1/015012

[44]

10.1016/j.cpc.2015.07.012

[45]

M. de Jong, W. Chen, T. Angsten, A. Jain, R. Notestine, A. Gamst, M. Sluiter, C. K. Ande, S. van der Zwaag, J. J. Plata, C. Toher, S. Curtarolo, G. Ceder, K. A. Persson, M. Asta, Charting the complete elastic properties of inorganic crystalline compounds. Sci. Data 2, 150009 (2015). 10.1038/sdata.2015.9

[46]

B. V. Suresh Solid State Devices and Technology (Pearson Education 2010).

[47]

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation

Anubhav Jain, Shyue Ping Ong, Geoffroy Hautier et al.

APL Materials 10.1063/1.4812323

[48]

A. A. Griffith, M. Eng, VI. The phenomena of rupture and flow in solids. Phil. Trans. R. Soc. Lond. A 221, 163–198 (1921). 10.1098/rsta.1921.0006

Cited By

752

In-situ metallic cobalt layer for multifunctional synergistic effects in high-performance Lithium metal batteries

Wenxing Xin, Qian Wang · 2026

Chemical Engineering Journal

Fluorinated electrolytes for lithium–sulfur and beyond-lithium metal–sulfur batteries

Avinash Raulo, Saheed Lateef · 2025

Energy Storage Materials

Decoding the Buried Interface: A Synergistic Framework for Mastering the Core Challenges of Solid‐State Batteries

Weiheng Chen, Jialong Wu · 2025

Small

Adaptive interphase enabled pressure-free all-solid-state lithium metal batteries

Guanjun Cen, Hailong Yu · 2025

Nature Sustainability

Fluorinated electrolyte formulations design enabling high-voltage and long-life lithium metal batteries

YuXin Rao, Xue Li · 2024

Nano Energy

LiF‐Rich Solid Electrolyte Interphase Formation by Establishing Sacrificial Layer on the Separator

Huding Jin, Seonmi Pyo · 2024

Small

High‐Areal‐Capacity and Long‐Cycle‐Life All‐Solid‐State Lithium‐Metal Battery by Mixed‐Conduction Interface Layer

Ming Yang, Yujing Wu · 2024

Advanced Energy Materials

Fluorine Chemistry in Rechargeable Batteries: Challenges, Progress, and Perspectives

Yao Wang, Xu Yang · 2024

Chemical Reviews

Dual‐Salt Electrolyte Additive Enables High Moisture Tolerance and Favorable Electric Double Layer for Lithium Metal Battery

Zuxin Wen, Wenqiang Fang · 2024

Angewandte Chemie International Edi...

Single-phase local-high-concentration solid polymer electrolytes for lithium-metal batteries

Volodymyr Koverga, Sufu Liu · 2024

Nature Energy

Constructing LiF-Dominated Interphases with Polymer Interwoven Outer Layer Enables Long-Term Cycling of Si Anodes

Yaozong Yang, Jie Wang · 2024

ACS Nano

Determining the Role of Ion Transport Throughput in Solid‐State Lithium Batteries

Ke Yang, Liang Zhao · 2023

Angewandte Chemie International Edi...

Fluorination in advanced battery design

Zhenzhen WU, Faezeh Makhlooghi Azad · 2023

Nature Reviews Materials

Designing electrolytes and interphases for high-energy lithium batteries

Hongli Wan, CHUNSHENG WANG · 2023

Nature Reviews Chemistry

Interface design for all-solid-state lithium batteries

Hongli Wan, Zeyi Wang · 2023

Nature

Achieving stable interphases toward lithium metal batteries by a dilute and anion-rich electrolyte

Dandan Chai, Yazhen Zhu · 2023

Energy Storage Materials

Critical interphase overpotential as a lithium dendrite-suppression criterion for all-solid-state lithium battery design

Hongli Wan, Zeyi Wang · 2023

Nature Energy

Recent progress and strategic perspectives of inorganic solid electrolytes: fundamentals, modifications, and applications in sodium metal batteries

Jiawen Huang, Kuan Wu · 2023

Chemical Society Reviews

In situ 3D crosslinked gel polymer electrolyte for ultra-long cycling, high-voltage, and high-safety lithium metal batteries

Jie Zhu, Jinping Zhang · 2023

Energy Storage Materials

Multifunctional electrospun PVDF-HFP gel polymer electrolyte membrane suppresses dendrite growth in anode-free li metal battery

Yosef Nikodimos, Wei-Nien Su · 2023

Energy Storage Materials

Metrics

752

Citations

48

References

Details

Published: Dec 07, 2018
Vol/Issue: 4(12)

Authors

X

Xiulin Fan

School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, PR China.; Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD 20740, USA.

X

Xiao Ji

Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD 20740, USA.; School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei 430074, PR China.

F

Fudong Han