Organocatalyzed atom transfer radical polymerization driven by visible light

Jordan C. Theriot; Chern-Hooi Lim; Haishen Yang; Matthew D. Ryan; Charles B. Musgrave; Garret M. Miyake

doi:10.1126/science.aaf3935

journal article May 27, 2016

Organocatalyzed atom transfer radical polymerization driven by visible light

Jordan C. Theriot Chern-Hooi Lim Haishen Yang Matthew D. Ryan Charles B. Musgrave

Garret M. Miyake

Science Vol. 352 No. 6289 pp. 1082-1086 · American Association for the Advancement of Science (AAAS)

View at Publisher Save 10.1126/science.aaf3935

Abstract

Precise control from a metal-free catalyst

Polymerization can be a rather dangerous free for all, with molecules joining randomly in chains at a chaotic pace. One of modern chemistry's great accomplishments has been the development of methods to assemble polymers in steady, orderly steps. However, order comes at a price, and often it's the need for metal catalysts that are hard to remove from the plastic product. Theriot
et al.
used theory to guide the design of a metal-free light-activated catalyst that offers precise control in atom transfer radical polymerization, alleviating concerns about residual metal contamination (see the Perspective by Shanmugam and Boyer).

Science
, this issue p.
1082
; see also p.
1053

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Metrics

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Citations

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References

Details

Published: May 27, 2016
Vol/Issue: 352(6289)
Pages: 1082-1086

Authors

J

Jordan C. Theriot

Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO 80309, USA.

C

Chern-Hooi Lim

Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO 80309, USA.; Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309, USA.

H

Haishen Yang

Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO 80309, USA.

M

Matthew D. Ryan

Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO 80309, USA.

C

Charles B. Musgrave

Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO 80309, USA.; Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309, USA.; Materials Science and Engineering Program, University of Colorado Boulder, Boulder, CO 80309, USA.

G

Garret M. Miyake

Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO 80309, USA.; Materials Science and Engineering Program, University of Colorado Boulder, Boulder, CO 80309, USA.

Funding

NSF Award: CHE-1214131

University of Colorado Boulder

Cite This Article

Jordan C. Theriot, Chern-Hooi Lim, Haishen Yang, et al. (2016). Organocatalyzed atom transfer radical polymerization driven by visible light. Science, 352(6289), 1082-1086. https://doi.org/10.1126/science.aaf3935

Organocatalyzed atom transfer radical polymerization driven by visible light

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