Classification of the External Magnetic Field Effects on the Photodecomposition Reaction of Dibenzoyl Peroxide

Yoshio Sakaguchi; Hisaharu Hayashi; Saburo Nagakura

doi:10.1246/bcsj.53.39

journal article Jan 01, 1980

Classification of the External Magnetic Field Effects on the Photodecomposition Reaction of Dibenzoyl Peroxide

Yoshio Sakaguchi Hisaharu Hayashi Saburo Nagakura

Bulletin of the Chemical Society of Japan Vol. 53 No. 1 pp. 39-42 · Oxford University Press (OUP)

View at Publisher Save 10.1246/bcsj.53.39

Abstract

Abstract
The external magnetic field effects upon product yields in the singlet sensitized photolysis of dibenzoyl peroxide in toluene were studied. The observed field dependencies were classified into four types, and were interpreted in terms of the electronic Zeeman and hyperfine interactions in the intermediate radical pair. Especially large magnetic field effects were observed for the yields of dimethylbiphenyls, new products in this reaction.

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References

18

[1]

[2]

10.1002/hlca.19780610215

[3]

[4]

[5]

[6]

[7]

10.1016/0009-2614(76)80807-x

[8]

10.1063/1.436013

[9]

10.1016/0301-0104(76)80097-3

[10]

10.1021/ja00491a061

[11]

10.1246/bcsj.51.2862

[12]

[13]

10.1246/bcsj.43.3315

[14]

[15]

10.1021/ja00772a006

[16]

10.1016/0040-4020(65)80033-3

[17]

10.1016/s0040-4020(01)98775-7

[18]

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Citations

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References

Details

Published: Jan 01, 1980
Vol/Issue: 53(1)
Pages: 39-42
License: View

Authors

Y

Yoshio Sakaguchi

The Institute for Solid State Physics, The University of Tokyo

H

Hisaharu Hayashi

The Institute of Physical and Chemical Research

S

Saburo Nagakura

The Institute for Solid State Physics, The University of Tokyo

Cite This Article

Yoshio Sakaguchi, Hisaharu Hayashi, Saburo Nagakura (1980). Classification of the External Magnetic Field Effects on the Photodecomposition Reaction of Dibenzoyl Peroxide. Bulletin of the Chemical Society of Japan, 53(1), 39-42. https://doi.org/10.1246/bcsj.53.39

Classification of the External Magnetic Field Effects on the Photodecomposition Reaction of Dibenzoyl Peroxide

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