journal article
Open Access
Jan 11, 2007
Synthesis of high ion exchange zeolites from coal fly ash
Abstract
This study focuses on the synthesis at a pilot plant scale of zeolitic material obtained from the coal fly ashes of the Teruel and Narcea power plants in Spain. After the optimisation of the synthesis parameters at laboratory scale, the Teruel and Narcea fly ashes were selected as low and high glass fly ashes. The pilot plant scale experiments were carried out in a 10 m3 reactor of Clariant SA (Barcelona, Spain). The results allowed obtaining 1.1 and 2.2 tonnes of zeolitic material with 40 and 55% of NaP1 content, in two single batch experiments of 24 and 8 hours, for Teruel and Narcea fly ashes, respectively. The cation exchange capacities (CEC) of the final product reached 2.0 and 2.7 meq g-1 for Teruel and Narcea zeolitic material, respectively, which are very close to the usual values reached by the high quality natural zeolitic products. Finally, with the aim of testing possible applications of the commercial NaP1-IQE and pilot plant NaP1-Narcea zeolitic products in water decontamination, efficiency for metal uptake from waste waters from electroplating baths was investigated.
Topics
No keywords indexed for this article. Browse by subject →
References
31
[1]
Allison, J.D., Brown, D.S., Novo-Gradac, K.J., 1991. MINTEQA2/PRODEFA2 - A geochemical assessment model for environmental systems - version 3.0 user’s manual, EPA/600/3-91/021, U.S. Environmental Protection Agency, Athens, Georgia.
[2]
Amrhein, Ch., Haghnia, G.H., Kim, T.S., Mosher, P.A., Gagajena, R.C., Amanios, T., de la Torre, L., 1996. Synthesis and properties of zeolites from coal fly ash. Environmental Science & Technology, 30, 735-742.
10.1021/es940482c
[3]
Bergk, K.H., Porsch, M., Drews, J., 1987. Conversion of solid primary and recycled raw materials to zeolite-containing products. Part VI. Continuous manufacture of zeolite A-containing products. Journal of Chemichal Technology Leipzig, 39, 308-310.
[4]
Berkgaut, V., Singer, A., 1996. High capacity cation exchanger by hydrothermal zeolitization of coal fly ash. Applied Clay Science, 10, 369-378.
10.1016/0169-1317(95)00033-x
[5]
Breck D.W., 1974. Zeolite molecular sieves, Zeolite Molecular Sieves. New York, John Wiley & Sons, 771 pp.
[6]
Höller, H., Wirsching, U., 1985. Zeolites formation from fly ash. Fortschritte der Mineralogie 63, 21-43.
[7]
Hollman, G.G., Steenbruggen, G., Janssen-Jurkoviková, M., 1999. A two-step process for the synthesis of zeolites from coal fly ash. Fuel, 78, 1225-1230.
10.1016/s0016-2361(99)00030-7
[8]
ISRIC (International Soil Reference and Information Centre), 1995. Procedures for soil analysis. Reference and Information Centre, FAO-UN, 9.1-9.13.
[9]
Kato, Y., Kakimoto, K., Ogawa, H., Tomari, M., 1986. Application of hydrothermally crystallized coal ash for wastewater treatment. Kogyo Yosui, 338, 37-45.
[10]
Kolousek, D., Seidl, V., Prochazkova, E., Obsasnikova, J., Kubelkova, L., Svetlik, I., 1993. Ecological utilization of power-plant fly ashes by their alteration to phillipsite: hydrothermal alteration, application. Acta Universitatis Carolinae Geologica, 1-2, 167-178.
[11]
Larosa, J.L., Kwan, S., Grutzeck, M.W., 1992. Zeolite formation in class f fly ash blended cement pastes. Journal of the American Ceramic Society, 75, 1574-1580.
10.1111/j.1151-2916.1992.tb04228.x
[12]
Lin, C.F., His, H.C., 1995. Resource recovery of waste fly ash: synthesis of zeolite-like materials. Environmental Science & Technology, 29, 1109-1117.
10.1021/es00004a033
[13]
Lin, C.F., Lo, S.S., Lin, H-Y., Lee, Y.J., 1998. Stabilization of cadmium contaminated soils using synthesized zeolite. Hazardous Materials. 60(3), 217-226.
10.1016/s0304-3894(98)00092-2
[14]
Mondragón, F., Rincón, F., Sierra, L., Escobar, C., Ramírez, J., Fernández, J., 1990. New perspectives for coal ash utilization: synthesis of zeolitic materials. Fuel, 69, 263-266.
10.1016/0016-2361(90)90187-u
[15]
Moreno, N., Querol, X., Ayora, C., Fernández-Pereira, C., Janssen-Jurkonicova, M., 2001a. Utilisation of zeolites synthesized from coal fly ash for the purification of acid mine waters. Environmental Science &Technology, 35, 3526-3534.
10.1021/es0002924
[16]
Moreno, N., Querol, X., Ayora, C., Alastuey, A., FernándezPereira, C., Janssen, M., 2001b. Potential environmental applications of pure zeolitic material synthesised from fly ash. Journal of Environmental Engineering, 127, 11, 994-1002.
10.1061/(asce)0733-9372(2001)127:11(994)
[17]
Park, M., Choi, J., 1995. Synthesis of phillipsite from fly ash. Clay Science, 9, 219-229.
[18]
Park, M., Choi, C.L., Lim, W.T., Kim, M.C., Choi, J., Heo, N.H., 2000a. Molten-salt method for the synthesis of zeolitic materials. I. Zeolite formation in alkaline moltensalt system. Microporous and Mesoporous Materials, 37, 81-89.
10.1016/s1387-1811(99)00196-1
[19]
Park, M., Choi, C.L., Lim, W.T., Kim, M.C., Choi, J., Heo, N.H., 2000b. Molten-salt method for the synthesis of zeolitic materials. II. Characterization of zeolitic materials. Microporous and Mesoporous Materials, 37, 91-98.
10.1016/s1387-1811(99)00195-x
[20]
Parkhurst, D.L., Appelo, C.A.J., 2002. User’s Guide to PHREEQC (Version 2) - A Computer Program for Speciation, Batch-Reaction, One-Dimensional Transport, and Inverse Geochemical Calculations. U.S.G.S. http://wwwbrr.cr.usgs.gov/projects0/GWC_coupled/phreeqc.
[21]
Patane, G., Mavillia, L., Corigliano, F., 1996. Chromium removal from wastewater by zeolitized waste materials. Materials Engineering, 7, 509-519.
[22]
Querol, X., Plana, F., Alastuey, A., Fernández-Turiel, J.L., López-Soler, A., 1995. Synthesis of industrial minerals from fly ash. Coal Science Series, 24, 1979-1982.
10.1016/s0167-9449(06)80210-7
[23]
Querol, X., Plana, F. Alastuey, A., López-Soler, A., 1997a. Synthesis of Na-zeolites from fly ash. Fuel, 76, 793-799.
10.1016/s0016-2361(96)00188-3
[24]
Querol, X., Alastuey, A., López-Soler, A., Plana, F., Andrés, J.M., Juan, R., Ferrer, P., Ruiz, C.R., 1997b. A fast method for recycling fly ash: Microwave–assisted zeolite synthesis. Environmental Science & Technology, 31, 2527-2533.
10.1021/es960937t
[25]
Querol X., Umaña, J.C., Plana, F., Alastuey, A., López-Soler, A., Medinaceli, A., Valero, A. Domingo, M.J., Garcia-Rojo, E, 2001. Synthesis of Na zeolites from fly ash in a pilot plant scale. Examples of potential environmental applications. Fuel, 80(6), 857-865.
10.1016/s0016-2361(00)00156-3
[26]
Rayalu, S., Meshram, S.U., Hasan, M.Z., 2000. Highly crystalline faujasitic zeolites from fly ash. Journal of Hazardous Materials, B77, 123-131.
10.1016/s0304-3894(00)00212-0
[27]
Rayalu, S., Udhoji, J.S., Munshi, K.N., Hasan, M.Z., 2001. Highly crystalline zeolite- a from fly ash of bituminous and lignite coal combustion. Journal of Hazardous Materials, B88, 107-121.
10.1016/s0304-3894(01)00296-5
[28]
Shigemoto, N., Shirakami, S., Hirano, S., Hayashi, H., 1992. Preparation and characterisation of zeolites from coal ash. Nippon Kagaku Kaishi, 5, 484-492.
10.1246/nikkashi.1992.484
[29]
Shih, W.H., Chang, H.L., Shen, Z., 1995. Conversion of class F fly ash to zeolite. Materials Research Society Symposium, Advances in Porous Materials, Boston, Materials Research Society Proceedings, 371, 39-44.
10.1557/proc-371-39
[30]
Singer, A., Berkgaut, V., 1995. Cation exchange properties of hidrothermally treated coal fly ash. Environmental Science & Technology, 29, 1748-1753.
10.1021/es00007a009
[31]
Suyama, Y., Katayama, K., Meguro, M., 1996. NH4+ - adsoption characteristics of zeolite synthetized from fly ash. Nippon Kagaku Kaishi, 2, 136-140.
10.1246/nikkashi.1996.136
Cited By
8
Simultaneous removal of Cd(II), Co(II), Cu(II), Pb(II), and Zn(II) ions from aqueous solutions via adsorption on FAU-type zeolites prepared from coal fly ash
Journal of Environmental Chemical E...
Ifeoma V. Joseph, Lubomira Tosheva · 2020
Metrics
8
Citations
31
References
Details
- Published
- Jan 11, 2007
- Pages
- 49-58
- License
- View
Authors
Cite This Article
X. Querol, N. Moreno, A. Alastuey, et al. (2007). Synthesis of high ion exchange zeolites from coal fly ash. Geologica Acta, 49-58. https://doi.org/10.1344/105.000000309
Related
You May Also Like
Mesozoic-Cenozoic stratigraphy of the Fuegian Andes, Argentina
E.B. OLIVERO, N. MALUMIÁN · 2008
25 citations
The Carboniferous System. Use of the new official names for the subsystems, series, and stages
P.H. HECKEL, G. CLAYTON · 2006
23 citations
Structural geology of the Fuegian Andes and Magallanes fold-and-thrust belt - Tierra del Fuego Island
M. Menichetti, E. Lodolo · 2008
18 citations
Statistical grid-based facies reconstruction and modelling for sedimentary bodies. Alluvial-palustrine and turbiditic examples
O. Falivene, L. Cabrera · 2007
16 citations
Magnetic mineralogy of Variscan granites from northern Portugal: an approach to their petrogenesis and metallogenic potential
C. Cruz, H. Sant'Ovaia · 2020
11 citations