journal article Mar 30, 2026

Microstructure and mechanical properties of a refractory Ti–Nb–Zr complex concentrated alloy produced by laser-based directed energy deposition (DED-LB)

View at Publisher Save 10.17073/0021-3438-2026-1-69-80
Abstract
This study investigates the microstructure and mechanical properties of a refractory Ti
2
NbZr complex concentrated alloy fabricated for the first time by laser-based directed energy deposition (DED-LB) from a pre-alloyed powder. The optimal processing parameters were identified; specifically, a laser power of 1600 W ensured a minimum porosity of 0.031 %. Comprehensive analysis revealed the formation of a single-phase BCC structure with a heterogeneous morphology, in which large columnar grains alternated with layers of fine equiaxed grains. The average grain size decreased with increasing specimen height. Mechanical testing demonstrated a favorable combination of strength and ductility, with a yield strength of ~810 MPa, an ultimate tensile strength of ~815 MPa, and an elongation of 16 %. A theoretical assessment of the contributions of the strengthening mechanisms showed good agreement with the experimental data. Solid-solution strengthening was found to make the dominant contribution to the alloy strength. The results confirm the potential of DED-LB for manufacturing high-quality Ti
2
NbZr components with mechanical properties superior to those of counterparts produced by conventional and additive technologies.
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References
31
[1]
Gorsse S., Couzinié J.P., Miracle D.B. From highentropy alloys to complex concentrated alloys. Comptes Rendus Physique. 2018;19(8):721—736. https://doi.org/10.1016/j.crhy.2018.09.004 10.1016/j.crhy.2018.09.004
[2]
Senkov O.N., Wilks G.B., Scott J.M., Miracle D.B. Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high entropy alloys. Intermetallics. 2011;19(5):698—706. https://doi.org/10.1016/j.intermet.2011.01.004 10.1016/j.intermet.2011.01.004
[3]
Wan Y., Cheng Y., Chen Y., Zhang Z., Liu Y., Gong H., Shen B., Liang X. A nitride-reinforced NbMoTaWHfN refractory high-entropy alloy with potential ultra-high-temperature engineering applications. Engineering. 2023;30:110—120. https://doi.org/10.1016/j.eng.2023.06.008 10.1016/j.eng.2023.06.008
[4]
Yurchenko N., Mirontsov V., Mishunina E., Kochura E., Stepanov N. A novel refractory complex concentrated alloy with ultra-high strength at 1200 °C. Scripta Materialia. 2026;271:116982. https://doi.org/10.1016/j.scriptamat.2025.116982 10.1016/j.scriptamat.2025.116982
[5]
Yurchenko N., Mishunina E., Kochura E., Mirontsov V., Kapustin D., Shalnova S., Evlashin S., Stepanov N. Design of refractory complex concentrated alloys combining good tensile strength and ductility at 22—1000 °C. International Journal of Refractory Metals and Hard Materials. 2025;132:107247. https://doi.org/10.1016/j.ijrmhm.2025.107247 10.1016/j.ijrmhm.2025.107247
[6]
Zhang C., Wang H., Wang X., Tang Y.T., Yu Q., Zhu C., Xu M., Zhao S., Kou R., Wang X., MacDonald B.E., Reed R.C., Vecchio K.S., Cao P., Rupert T.J., Lavernia E.J. Strong and ductile refractory high-entropy alloys with super formability. Acta Materialia. 2023;245:118602. https://doi.org/10.1016/j.actamat.2022.118602 10.1016/j.actamat.2022.118602
[7]
Cook D.H., Kumar P., Payne M.I., Belcher C.H., Borges P., Wang W., Walsh F., Li Z., Devaraj A., Zhang M., Asta M., Minor A.M., Lavernia E.J., Apelian D., Ritchie R.O. Kink bands promote exceptional fracture resistance in a NbTaTiHf refractory medium-entropy alloy. Science. 2024;384(6692):178—84. https://doi.org/10.1126/science.adn2428 10.1126/science.adn2428
[8]
Zeng S., Zhu Y., Li W., Zhang H., Zhang H., Zhu Z. A single-phase Ti3Zr1.5NbVAl0.25 refractory high entropy alloy with excellent combination of strength and toughness. Materials Letters. 2022;323:132548. https://doi.org/10.1016/j.matlet.2022.132548 10.1016/j.matlet.2022.132548
[9]
Gorr B., Müller F., Schellert S., Christ H.J., Chen H., Kauffmann A., Heilmaier M. A new strategy to intrinsically protect refractory metal based alloys at ultra high temperatures. Corrosion Science. 2020;166:108475. https://doi.org/10.1016/j.corsci.2020.108475 10.1016/j.corsci.2020.108475
[10]
Piscopo G., Iuliano L. Current research and industrial application of laser powder directed energy deposition. The International Journal of Advanced Manufacturing Technology. 2022;119(11):6893—6917. https://doi.org/10.1007/s00170-021-08596-w 10.1007/s00170-021-08596-w
[11]
Dobbelstein H., Thiele M., Gurevich E.L., George E.P., Ostendorf A. Direct metal deposition of refractory high entropy alloy MoNbTaW. Physics Procedia. 2016;83: 624—633. https://doi.org/10.1016/j.phpro.2016.08.065 10.1016/j.phpro.2016.08.065
[12]
Dobbelstein H., Gurevich E.L., George E.P., Ostendorf A., Laplanche G. Laser metal deposition of a refractory TiZrNbHf Ta high-entropy alloy. Additive Manufacturing. 2018;24:386—390. https://doi.org/10.1016/j.addma.2018.10.008 10.1016/j.addma.2018.10.008
[13]
Moorehead M., Bertsch K., Niezgoda M., Parkin C., Elbakhshwan M., Sridharan K., Zhang C., Thoma D., Couet A. High-throughput synthesis of Mo—Nb—Ta—W high-entropy alloys via additive manufacturing. Materials & Design. 2020;187:108358. https://doi.org/10.1016/j.matdes.2019.108358 10.1016/j.matdes.2019.108358
[14]
Gou S., Gao M., Shi Y., Li S., Fang Y., Chen X., Chen H., Yin W., Liu J., Lei Z., Wang H. Additive manufacturing of ductile refractory high-entropy alloys via phase engineering. Acta Materialia. 2023;248:118781. https://doi.org/10.1016/j.actamat.2023.118781 10.1016/j.actamat.2023.118781
[15]
Zhang Y., Wang H., Zhu Y., Zhang S., Cheng F., Yang J., Su B., Yang C. High specific yield strength and superior ductility of a lightweight refractory high-entropy alloy prepared by laser additive manufacturing. Additive Manufacturing. 2023;77:103813. https://doi.org/10.1016/j.addma.2023.103813 10.1016/j.addma.2023.103813
[16]
Preisler D., Krajňák T., Janeček M., Kozlík J., Stráský J., Brázda M., Džugan J. Directed energy deposition of bulk Nb—Ta—Ti—Zr refractory complex concentrated alloy. Materials Letters. 2023;337:133980. https://doi.org/10.1016/j.matlet.2023.133980 10.1016/j.matlet.2023.133980
[17]
Cui D., Guo B., Yang Z., Liu X., Wang Z., Li J., Wang J., He F. Unraveling microstructure and mechanical response of an additively manufactured refractory TiVHfNbMo high-entropy alloy. Additive Manufacturing. 2024;84:104126. https://doi.org/10.1016/j.addma.2024.104126 10.1016/j.addma.2024.104126
[18]
Zhang Y., Qin B., Ouyang D., Liu L., Feng C., Yan Y., Ye S., Ke H., Chan K.C., Wang W. Strong yet ductile refractory high entropy alloy fabricated via additive manufacturing. Additive Manufacturing. 2024;81:104009. https://doi.org/10.1016/j.addma.2024.104009 10.1016/j.addma.2024.104009
[19]
Yang Q., Cai X., Huang L., Dong P., Ren C., Zhou Y., Li J., Shuai M. High strength-ductile lightweight Al— Ti—Zr—Nb—Ta refractory high-entropy alloy via laser directed energy deposition. Materials Science and Engineering: A. 2025;924:147831. https://doi.org/10.1016/j.msea.2025.147831 10.1016/j.msea.2025.147831
[20]
Li Y., Yang Y., Xie J., Chen L., Zhang X. Effect of cooling rate on microstructure and mechanical properties of AlMo0.5NbTa0.5TiZr refractory high-entropy alloy prepared by laser metal deposition. Materials Science and Engineering: A. 2025;942:148734. https://doi.org/10.1016/j.msea.2025.148734 10.1016/j.msea.2025.148734
[21]
Li J., Wang C., Wang T., Wang W., Chai L., Luo J. High-temperature wear mechanisms and oxidation properties of MoNbTaWTi refractory high entropy alloy prepared by direct laser deposition. International Journal of Refractory Metals and Hard Materials. 2025;128:107025. https://doi.org/10.1016/j.ijrmhm.2024.107025 10.1016/j.ijrmhm.2024.107025
[22]
Cui D., Zhang S., Wang S., Bai X., Li C, Chen J, Wei B., Hou K., Ramaurty U., Wang J., He F. Processing defects and damage mechanisms in refractory high-entropy alloys additively manufactured via directed energy deposition. Journal of Materials Science & Technology. 2026;258:170—186. https://doi.org/10.1016/j.jmst.2025.09.034 10.1016/j.jmst.2025.09.034
[23]
Senkov O.N., Rao S., Chaput K.J., Woodward C. Compositional effect on microstructure and properties of NbTiZr-based complex concentrated alloys. Acta Materialia. 2018;151:201—215. https://doi.org/10.1016/j.actamat.2018.03.065 10.1016/j.actamat.2018.03.065
[24]
Yurchenko N., Panina E., Zherebtsov S., Stepanov N. Design and characterization of eutectic refractory high entropy alloys. Materialia. 2021;16:101057. https://doi.org/10.1016/j.mtla.2021.101057 10.1016/j.mtla.2021.101057
[25]
Eleti R.R., Stepanov N., Yurchenko N., Zherebtsov S., Maresca F. Cross-kink unpinning controls the mediumto high-temperature strength of body-centered cubic NbTiZr medium-entropy alloy. Scripta Materialia. 2022;209:114367. https://doi.org/10.1016/j.scriptamat.2021.114367 10.1016/j.scriptamat.2021.114367
[26]
An Y., Liu Y., Liu S., Zhang B., Yang G., Zhang C., Tan X., Ding J., Ma E. Additive manufacturing of a strong and ductile oxygen-doped NbTiZr medium-entropy alloy. Materials Futures. 2025;4(1):015001. https://doi.org/10.1088/2752-5724/ad8df2 10.1088/2752-5724/ad8df2
[27]
Yan X., Zhang Y. A body-centered cubic Zr50Ti35Nb15 medium-entropy alloy with unique properties. Scripta Materialia. 2020;178:329—333. https://doi.org/10.1016/j.scriptamat.2019.11.059 10.1016/j.scriptamat.2019.11.059
[28]
Chen Y., Xu Z., Wang M., Li Y., Wu C., Yang Y. A singlephase V0.5Nb0.5ZrTi refractory high-entropy alloy with outstanding tensile properties. Materials Science and Engineering: A. 2020;792:139774. https://doi.org/10.1016/j.msea.2020.139774 10.1016/j.msea.2020.139774
[29]
Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy

O.N. Senkov, J.M. Scott, S.V. Senkova et al.

Journal of Alloys and Compounds 10.1016/j.jallcom.2011.02.171
[30]
Senkov O.N., Rao S.I., Butler T.M., Daboiku T.I., Chaput K.J. Microstructure and properties of Nb—Mo—Zr based refractory alloys. International Journal of Refractory Metals and Hard Materials. 2020;92:105321. https://doi.org/10.1016/j.ijrmhm.2020.105321 10.1016/j.ijrmhm.2020.105321
[31]
Cordero Z.C., Knight B.E., Schuh C.A. Six decades of the Hall—Petch effect — a survey of grain-size strengthening studies on pure metals. International Materials Reviews. 2016;61(8):495—512. https://journals.sagepub.com/doi/10.1080/09506608.2016.11918 10.1080/09506608.2016.1191808
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Published
Mar 30, 2026
Vol/Issue
(1)
Pages
69-80
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Cite This Article
I. V. Krasanov, A. D. Evstifeev, N. R. Alymov, et al. (2026). Microstructure and mechanical properties of a refractory Ti–Nb–Zr complex concentrated alloy produced by laser-based directed energy deposition (DED-LB). Izvestiya. Non-Ferrous Metallurgy(1), 69-80. https://doi.org/10.17073/0021-3438-2026-1-69-80