journal article Open Access Aug 08, 2025

Vapor-Deposited Inorganic Perovskite Solar Cells from Fundamentals to Scalable Commercial Pathways

Electronics Vol. 14 No. 16 pp. 3171 · MDPI AG
View at Publisher Save 10.3390/electronics14163171
Abstract
Inorganic halide perovskites have garnered significant attention as promising candidates for photovoltaic and optoelectronic applications, owing to their enhanced thermal and chemical stability relative to hybrid perovskite materials. This review synthesizes recent progress in vapor-phase deposition methodologies, such as co-evaporation, close space sublimation (CSS), continuous flash sublimation (CFS), and chemical vapor deposition (CVD), which enable the precise modulation of film composition and morphology. Advances in material systems, including the stabilization of CsPbI2Br, the introduction of tin-doped phases, and the investigation of lead-free double perovskites like Cs2AgSbI6 and Cs2AgBiCl6, are critically evaluated with respect to their impact on device performance. The incorporation of these materials into photovoltaic devices and tandem configurations is explored, with particular emphasis on improvements in power conversion efficiency and operational durability. Furthermore, interface engineering approaches tailored to vacuum-deposited films—such as defect passivation and energy-level alignment—are examined in detail. The potential for scalable manufacturing is assessed through simulation analyses, throughput modeling, and pilot-scale demonstrations, underscoring the feasibility of industrial-scale production. By offering a comprehensive overview of these advancements, this review provides valuable perspectives on the current landscape and prospective trajectories of vapor-deposited inorganic perovskite technologies.
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References
49
[1]
The Main Progress of Perovskite Solar Cells in 2020–2021

Tianhao Wu, Zhenzhen Qin, Yulan Wang et al.

Nano-Micro Letters 2021 10.1007/s40820-021-00672-w
[2]
Zhou "Annual research review of perovskite solar cells in 2023" Mater. Futures (2024) 10.1088/2752-5724/ad42ba
[3]
The Promise and Challenges of Inverted Perovskite Solar Cells

Peng Chen, Yun Xiao, Xiaohan Jia et al.

Chemical Reviews 2024 10.1021/acs.chemrev.4c00073
[4]
Ullah "All-inorganic CsPbBr3 perovskite: A promising choice for photovoltaics" Mater. Adv. (2021) 10.1039/d0ma00866d
[5]
Du "Ionic liquid treatment for highest-efficiency ambient printed stable all-inorganic CsPbI3 perovskite solar cells" Adv. Mater. (2022) 10.1002/adma.202106750
[6]
Ullah "Comprehensive assessment of all-inorganic CsPbI3–xBrx perovskite-based solar cells: Interface engineering, stability, and economic aspects" Coord. Chem. Rev. (2024) 10.1016/j.ccr.2024.215957
[7]
Fu "In situ stabilized CsPbI3 for air-fabricated inverted inorganic perovskite photovoltaics with wide humidity operating window" Adv. Funct. Mater. (2022) 10.1002/adfm.202111116
[8]
Hutter "Vapour-deposited cesium lead iodide perovskites: Microsecond charge carrier lifetimes and enhanced photovoltaic performance" ACS Energy Lett. (2017) 10.1021/acsenergylett.7b00591
[9]
Chiang "Vacuum-deposited wide-bandgap perovskite for all-perovskite tandem solar cells" ACS Energy Lett. (2023) 10.1021/acsenergylett.3c00564
[10]
Bonomi "Physical and chemical vapor deposition methods applied to all-inorganic metal halide perovskites" J. Vac. Sci. Technol. A (2020) 10.1116/6.0000568
[11]
Ullah "Evaporation Deposition Strategies for All-Inorganic CsPb(I1–xBrx)3 Perovskite Solar Cells: Recent Advances and Perspectives" Sol. Rrl (2021) 10.1002/solr.202100172
[12]
Ihrenberger "Solution-free growth of CsPbBr3 perovskite films using a fast and scalable close space sublimation method" Cryst. Growth Des. (2024) 10.1021/acs.cgd.4c00249
[13]
Petry "Industrialization of perovskite solar cell fabrication: Strategies to achieve high-throughput vapor deposition processes" EES Sol. (2025) 10.1039/d5el00069f
[14]
Soltanpoor "Pressing challenges of halide perovskite thin film growth" APL Mater. (2020) 10.1063/5.0027573
[15]
Nucleation and growth of thin films

J A Venables, G D T Spiller, M Hanbucken

Reports on Progress in Physics 1984 10.1088/0034-4885/47/4/002
[16]
Guesnay "Vapor deposition of metal halide perovskite thin films: Process control strategies to shape layer properties" APL Mater. (2021) 10.1063/5.0060642
[17]
Zhang "Efficient thermally evaporated γ-CsPbI3 perovskite solar cells" Adv. Energy Mater. (2021) 10.1002/aenm.202100299
[18]
Abib "Direct deposition of Sn-doped CsPbBr3 perovskite for efficient solar cell application" RSC Adv. (2021) 10.1039/d0ra09202a
[19]
Lee "Controlled Crystal Growth of All-Inorganic CsPbI2Br via Sequential Vacuum Deposition for Efficient Perovskite Solar Cells" ACS Nano (2024) 10.1021/acsnano.4c03079
[20]
Gupta "Photostable Inorganic Perovskite Absorber via Thermal Evaporation for Monolithic Perovskite/Perovskite/Silicon Triple-Junction Solar Cells" Prog. Photovolt. Res. Appl. (2025) 10.1002/pip.3923
[21]
Morsa "Single-vs dual-source vapor deposition of inorganic halide perovskites: A case study of CsPbBr3" APL Mater. (2025) 10.1063/5.0242134
[22]
Liu "High-quality and full-coverage CsPbBr3 thin films via electron beam evaporation with post-annealing treatment for all-inorganic perovskite solar cells" Sol. Energy (2022) 10.1016/j.solener.2022.01.009
[23]
Su "Crystallization mechanism and lasing properties of CsPbBr3 perovskites by chemical vapor deposition" Chem. Eng. J. (2023) 10.1016/j.cej.2023.144906
[24]
Abzieher "Continuous flash sublimation of inorganic halide perovskites: Overcoming rate and continuity limitations of vapor deposition" J. Mater. Chem. A (2024) 10.1039/d3ta05881f
[25]
Zhou "Stable CsPbX3 mixed halide alloyed epitaxial films prepared by pulsed laser deposition" Appl. Phys. Lett. (2022) 10.1063/5.0081955
[26]
Kralj "Single-source pulsed laser-deposited perovskite solar cells with enhanced performance via bulk and 2D passivation" Joule (2024) 10.1016/j.joule.2024.09.001
[27]
Kralj "Template-assisted growth of CsxFA1-xPbI3 with pulsed laser deposition for single junction perovskite solar cells" Adv. Energy Mater. (2025) 10.1002/aenm.202406033
[28]
Hwang, J.-K., Jeong, S.-H., Kim, D., Lee, H.-S., and Kang, Y. (2023). A review on dry deposition techniques: Pathways to enhanced perovskite solar cells. Energies, 16. 10.3390/en16165977
[29]
Abzieher "Vapor phase deposition of perovskite photovoltaics: Short track to commercialization?" Energy Environ. Sci. (2024) 10.1039/d3ee03273f
[30]
Rodkey "Close-space sublimation as a scalable method for perovskite solar cells" ACS Energy Lett. (2024) 10.1021/acsenergylett.3c02794
[31]
Lu, X., Fan, X., Zhang, H., Xu, Q., and Ijaz, M. (2024). Review on preparation of perovskite solar cells by pulsed laser deposition. Inorganics, 12. 10.3390/inorganics12050128
[32]
Kliner "Pulsed Laser Deposition of Halide Perovskites with over 10-Fold Enhanced Deposition Rates" J. Phys. Chem. Lett. (2025) 10.1021/acs.jpclett.5c00047
[33]
Huang "Vapor-deposited CsPbI3 solar cells demonstrate an efficiency of 16" Sci. Bull. (2021) 10.1016/j.scib.2020.12.024
[34]
Duan "Highly efficient and stable inorganic CsPbBr3 perovskite solar cells via vacuum co-evaporation" Appl. Surf. Sci. (2021) 10.1016/j.apsusc.2021.150153
[35]
Liao "Performance enhancement of evaporated CsPbI2Br perovskite solar cells with a CuSCN hole transport layer via a cesium bromide buffer layer" ACS Appl. Energy Mater. (2022) 10.1021/acsaem.2c01155
[36]
Guo "Effective defect passivation with a designer ionic molecule for high-efficiency vapour-deposited inorganic phase-pure CsPbBr 3 perovskite solar cells" J. Mater. Chem. A (2023) 10.1039/d2ta06092b
[37]
Angel "Thermally Evaporated CsPbBr3 for Green Perovskite Light-Emitting Diodes: Challenges and Perspectives" ACS Appl. Electron. Mater. (2025) 10.1021/acsaelm.4c02191
[38]
Pokharel "Vacuum-deposited cesium tin iodide thin films with tunable thermoelectric properties" ACS Appl. Energy Mater. (2022) 10.1021/acsaem.2c01936
[39]
Reo "Vapour-deposited high-performance tin perovskite transistors" Nat. Electron. (2025) 10.1038/s41928-025-01380-8
[40]
Bonomi "Versatile vapor phase deposition approach to cesium tin bromide materials CsSnBr3, CsSn2Br5 and Cs2SnBr6" RSC Adv. (2020) 10.1039/d0ra04680a
[41]
Jung "Vapor phase deposition of lead-free halide perovskite alloy CsSn1−xZnxBr3" Jpn. J. Appl. Phys. (2023) 10.35848/1347-4065/acfdb3
[42]
Yin "Space-Confined Chemical Vapor Deposition Synthesis of All-Inorganic CsSnI3 Perovskite Nanosheets" J. Phys. Chem. C (2024) 10.1021/acs.jpcc.4c01819
[43]
Li "Suppressed Defects and Improved Stability of All-Inorganic CsSnI3 Films by Solid Additive-Assisted Chemical Vapor Deposition Process" Small (2025) 10.1002/smll.202412824
[44]
Horani "Cs2AgSbI6 Nanocrystals: A New Air-Stable Iodide Double-Perovskite (Elpasolite) Semiconductor" J. Am. Chem. Soc. (2025) 10.1021/jacs.5c03942
[45]
Jain "Vapor Deposition and Optical Properties of Cs2AgBiCl6 Thin Films" J. Phys. Chem. C (2025) 10.1021/acs.jpcc.4c06622
[46]
Goldberg "All-evaporated, all-inorganic CsPbI3 Perovskite-based devices for broad-band photodetector and solar cell applications" ACS Appl. Electron. Mater. (2021) 10.1021/acsaelm.1c00252
[47]
Zhang, J., Wang, C., Shen, C., Chen, M., He, B., Su, Z., Cao, L., and Gao, X. (2025). Distinct rubrene/CsPbI2Br interfacial energetics on spin-coated and vacuum evaporated perovskite films. Appl. Surf. Sci., 163663. 10.1016/j.apsusc.2025.163663
[48]
Xu "Surface Energy-Assisted Patterning of Vapor Deposited All-Inorganic Perovskite Arrays for Wearable Optoelectronics" Adv. Sci. (2024) 10.1002/advs.202402635
[49]
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References
Details
Published
Aug 08, 2025
Vol/Issue
14(16)
Pages
3171
License
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Funding
National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) Award: NRF-RS-2023-00212744
Chung-Ang University Research Grants Award: NRF-RS-2023-00212744
Cite This Article
Padmini Pandey, Dong-Won Kang (2025). Vapor-Deposited Inorganic Perovskite Solar Cells from Fundamentals to Scalable Commercial Pathways. Electronics, 14(16), 3171. https://doi.org/10.3390/electronics14163171
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