Characterization and Corrosion Resistance of Boron-Containing-Austenitic Stainless Steels Produced by Rapid Solidification Techniques

Guilherme Y. Koga; Lucas B. Otani; Ana M. B. Silva; Virginie Roche; Ricardo P. Nogueira; Alberto Moreira Jorge Junior; Claudemiro Bolfarini; Claudio S. Kiminami; Walter J. Botta

doi:10.3390/ma11112189

journal article Open Access Nov 05, 2018

Characterization and Corrosion Resistance of Boron-Containing-Austenitic Stainless Steels Produced by Rapid Solidification Techniques

Guilherme Y. Koga Lucas B. Otani

Ana M. B. Silva Virginie Roche Ricardo P. Nogueira

Alberto Moreira Jorge Junior Claudemiro Bolfarini Claudio S. Kiminami Walter J. Botta

Materials Vol. 11 No. 11 pp. 2189 · MDPI AG

View at Publisher Save 10.3390/ma11112189

Abstract

The composition of a commercial duplex stainless steel was modified with boron additions (3.5, 4.5, and 5.5 wt.%) and processed by rapid-quenching techniques: Melt-spinning, copper-mold casting, and high-velocity oxygen fuel (HVOF). Spray deposition was also used to produce alloys as the process may induce rapid-solidified-like microstructures. These processing routes led to microstructures with distinguished corrosion resistance. Among the alloys with different boron contents, the 63.5Fe25Cr7Ni4.5B composition enabled the production of fully amorphous ribbons by melt-spinning. The cooling rate experienced during copper-mold casting, high-velocity oxygen fuel, and spray deposition did not ensure complete amorphization. The crystalline phases thereby formed were (Fe,Cr)2B and (Fe,Mo)3B2 borides in an austenitic-matrix with morphology and refinement dependent of the cooling rates. Fully amorphous 63.5Fe25Cr7Ni4.5B ribbons exhibited outstanding corrosion resistance in chloride-rich alkaline and acid media with negligible corrosion current densities of about 10−8 A/cm² and a broad passivation plateau. Although the specimens of the same composition produced by HVOF process and spray deposition exhibited lower corrosion resistance because of intrinsic porosity and crystalline phases, their corrosion behaviors were superior to those of AISI 1045 steel used as substrate with the advantage to be reinforced with hard borides known to be resistant against wear.

Topics

No keywords indexed for this article. Browse by subject →

References

38

[1]

Lavernia "The rapid solidification processing of materials: Science, principles, technology, advances, and applications" J. Mater. Sci. (2010) 10.1007/s10853-009-3995-5

[2]

Recent development and application products of bulk glassy alloys

A. Inoue, A. Takeuchi

Acta Materialia 2011 10.1016/j.actamat.2010.11.027

[3]

Tsai "Prominent Fe-based bulk amorphous steel alloy with large supercooled liquid region and superior corrosion resistance" J. Alloys Compd. (2014) 10.1016/j.jallcom.2013.09.186

[4]

Inoue "Development and applications of Fe- and Co-based bulk glassy alloys and their prospects" J. Alloys Compd. (2014) 10.1016/j.jallcom.2013.11.122

[5]

Hou, X., Du, D., Wang, K., Hong, Y., and Chang, B. (2018). Microstructure and Wear Resistance of Fe-Cr-Mo-Co-C-B Amorphous Composite Coatings Synthesized by Laser Cladding. Metals, 8. 10.3390/met8080622

[6]

Iron-based bulk metallic glasses

C Suryanarayana, A Inoue

International Materials Reviews 2013 10.1179/1743280412y.0000000007

[7]

Li, Z., Zhou, S., Zhang, G., and Zheng, W. (2018). Highly Ductile and Ultra-Thick P-Doped FeSiB Amorphous Alloys with Excellent Soft Magnetic Properties. Materials, 11. 10.3390/ma11071148

[8]

Weng, N., Wang, F., Qin, F., Tang, W., and Dan, Z. (2017). Enhanced Azo-Dyes Degradation Performance of Fe-Si-B-P Nanoporous Architecture. Materials, 10. 10.3390/ma10091001

[9]

Aboki "Development of Fe-B Based Bulk Metallic Glasses: Morphology of Residual Phases in Fe50Ni16Mo6B18Zr10 Glass" Metals (2013) 10.3390/met3020159

[10]

Lu "Role of minor alloying additions in formation of bulk metallic glasses: A Review" J. Mater. Sci. (2004) 10.1023/b:jmsc.0000031478.73621.64

[11]

Liu "Effect of minor alloying additions on glass formation in bulk metallic glasses" Intermetallics (2005) 10.1016/j.intermet.2004.07.034

[12]

Inoue "Bulk amorphous FC20 (Fe-C-Si) alloys with small amounts of B and their crystallized structure and mechanical properties" Acta Mater. (2000) 10.1016/s1359-6454(99)00394-8

[13]

Cheney "Development of quaternary Fe-based bulk metallic glasses" Mater. Sci. Eng. A (2008) 10.1016/j.msea.2008.03.019

[14]

Zhou "Formation and corrosion behavior of Fe-based amorphous metallic coatings by HVOF thermal spraying" Surf. Coat. Technol. (2009) 10.1016/j.surfcoat.2009.08.025

[15]

Koga "Corrosion properties of Fe–Cr–Nb–B amorphous alloys and coatings" Surf. Coat. Technol. (2014) 10.1016/j.surfcoat.2014.06.022

[16]

Zheng "Erosion–corrosion of HVOF-sprayed Fe-based amorphous metallic coating under impingement by a sand-containing NaCl solution" Corros. Sci. (2013) 10.1016/j.corsci.2013.07.006

[17]

Koga "Microstructure and wear behavior of Fe-based amorphous HVOF coatings produced from commercial precursors" Surf. Coat. Technol. (2017) 10.1016/j.surfcoat.2016.10.057

[18]

Grant "Solidification in spray forming" Metall. Mater. Trans. A (2007) 10.1007/s11661-006-9015-3

[19]

Rios "Characterization of Glass Forming Alloy Fe43.2Co28.8B19.2Si4.8Nb4 Processed by Spray Forming and Wedge Mold Casting Techniques" Mater. Sci. Forum (2011) 10.4028/www.scientific.net/msf.691.23

[20]

Kiminami "Processing of glass former alloys by spray forming. Herstellung von Legierungen für Glasformen durch Sprühkompaktieren" Materwiss. Werksttech. (2010) 10.1002/mawe.201000637

[21]

Duarte "Element-resolved corrosion analysis of stainless-type glass-forming steels" Science (2013) 10.1126/science.1230081

[22]

Cottis, B., Graham, M., Lindsay, R., Lyon, S., Richardson, T., Scantlebury, D., and Stott, H. (2010). Corrosion of amorphous and nanograined alloys. Shreir’s Corrosion, Elsevier Inc.

[23]

Madinehei "Glass-formation and corrosion properties of Fe–Cr–Mo–C–B glassy ribbons with low Cr content" J. Alloys Compd. (2014) 10.1016/j.jallcom.2013.12.245

[24]

Pang "Bulk glassy Fe-Cr-Mo-C-B alloys with high corrosion resistance" Corros. Sci. (2002) 10.1016/s0010-938x(02)00002-1

[25]

Sudarshan, T.S., and Srivatsan, T.S. (1993). Rapid Solidification Technology: An Engineering Guide, Technomic Publishing Company, Inc.. [1st ed.].

[26]

Zepon "Electrochemical Corrosion Behavior of Spray-Formed Boron-Modified Supermartensitic Stainless Steel" Metall. Mater. Trans. A (2017) 10.1007/s11661-017-3980-6

[27]

Microstructural investigation of Fe Cr Nb B amorphous/nanocrystalline coating produced by HVOF

Y. Guo, G.Y. Koga, A. Moreira Jorge et al.

Materials & Design 2016 10.1016/j.matdes.2016.09.027

[28]

Koga "Production and Corrosion Resistance of Thermally Sprayed Fe-Based Amorphous Coatings from Mechanically Milled Feedstock Powders" Metall. Mater. Trans. A (2018) 10.1007/s11661-018-4785-y

[29]

Sundman "The Thermo-Calc databank system" Calphad (1985) 10.1016/0364-5916(85)90021-5

[30]

Yao "Boron content dependence of crystallization, glass forming ability and magnetic properties in amorphous Fe-Zr-B-Nb alloys" J. Alloys Compd. (2004) 10.1016/j.jallcom.2003.08.096

[31]

Gupta "Non-crystalline solids: Glasses and amorphous solids" J. Non-Cryst. Solids (1996) 10.1016/0022-3093(95)00502-1

[32]

Farmer "Corrosion resistance of thermally sprayed high-boron iron-based amorphous-metal coatings: Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4" J. Mater. Res. (2007) 10.1557/jmr.2007.0291

[33]

Soyama "Microstructure formation and abrasive wear resistance of a boron-modified superduplex stainless steel produced by spray forming" J. Mater. Res. (2016) 10.1557/jmr.2016.323

[34]

Upadhyay "Pitting corrosion studies on solution-annealed borated type 304l stainless steel using electrochemical noise technique" Corrosion (2014) 10.5006/1098

[35]

Chan "Effect of Secondary Phase Precipitation on the Corrosion Behavior of Duplex Stainless Steels" Materials (2014) 10.3390/ma7075268

[36]

Wang "Effect of porosity sealing treatments on the corrosion resistance of high-velocity oxy-fuel (HVOF)-sprayed Fe-based amorphous metallic coatings" Surf. Coat. Technol. (2011) 10.1016/j.surfcoat.2011.08.045

[37]

Zhang "Effect of porosity defects on the long-term corrosion behaviour of Fe-based amorphous alloy coated mild steel" Corros. Sci. (2016) 10.1016/j.corsci.2016.04.021

[38]

Zepon "Design of wear resistant boron-modified supermartensitic stainless steel by spray forming process" Mater. Des. (2015) 10.1016/j.matdes.2015.06.020

Metrics

21

Citations

38

References

Details

Published: Nov 05, 2018
Vol/Issue: 11(11)
Pages: 2189
License: View

Authors

G

Guilherme Y. Koga

Department of Materials Science and Engineering, Federal University of São Carlos, Rod. Washington Luis, km 235, CEP 13565-905 São Carlos, SP, Brazil; LEPMI, UMR5279 CNRS, Grenoble INP, Université Grenoble Alpes, 1130, rue de la piscine, BP 75, 38402 Saint Martin d’Hères, France

L

Lucas B. Otani

Department of Materials Science and Engineering, Federal University of São Carlos, Rod. Washington Luis, km 235, CEP 13565-905 São Carlos, SP, Brazil

A

Ana M. B. Silva

Department of Materials Science and Engineering, Federal University of São Carlos, Rod. Washington Luis, km 235, CEP 13565-905 São Carlos, SP, Brazil

V

Virginie Roche

LEPMI, UMR5279 CNRS, Grenoble INP, Université Grenoble Alpes, 1130, rue de la piscine, BP 75, 38402 Saint Martin d’Hères, France

R

Ricardo P. Nogueira

LEPMI, UMR5279 CNRS, Grenoble INP, Université Grenoble Alpes, 1130, rue de la piscine, BP 75, 38402 Saint Martin d’Hères, France; Gas Research Center, Khalifa University of Science and Technology, P.O. Box 2533, Abu Dhabi, UAE

A

Alberto Moreira Jorge Junior

Department of Materials Science and Engineering, Federal University of São Carlos, Rod. Washington Luis, km 235, CEP 13565-905 São Carlos, SP, Brazil; LEPMI, UMR5279 CNRS, Grenoble INP, Université Grenoble Alpes, 1130, rue de la piscine, BP 75, 38402 Saint Martin d’Hères, France

C

Claudemiro Bolfarini

Department of Materials Science and Engineering, Federal University of São Carlos, Rod. Washington Luis, km 235, CEP 13565-905 São Carlos, SP, Brazil

C

Claudio S. Kiminami

Department of Materials Science and Engineering, Federal University of São Carlos, Rod. Washington Luis, km 235, CEP 13565-905 São Carlos, SP, Brazil

W

Walter J. Botta

Department of Materials Science and Engineering, Federal University of São Carlos, Rod. Washington Luis, km 235, CEP 13565-905 São Carlos, SP, Brazil; LEPMI, UMR5279 CNRS, Grenoble INP, Université Grenoble Alpes, 1130, rue de la piscine, BP 75, 38402 Saint Martin d’Hères, France

Funding

Fundação de Amparo a Pesquisa do Estado de São Paulo Award: 2013/05987-8

Cite This Article

Guilherme Y. Koga, Lucas B. Otani, Ana M. B. Silva, et al. (2018). Characterization and Corrosion Resistance of Boron-Containing-Austenitic Stainless Steels Produced by Rapid Solidification Techniques. Materials, 11(11), 2189. https://doi.org/10.3390/ma11112189

Characterization and Corrosion Resistance of Boron-Containing-Austenitic Stainless Steels Produced by Rapid Solidification Techniques

You May Also Like