Metal-Organic-Framework FeBDC-Derived Fe3O4 for Non-Enzymatic Electrochemical Detection of Glucose

Syauqi Abdurrahman Abrori; Ni Luh Wulan Septiani; Nugraha; Isa Anshori; Suyatman; Veinardi Suendo; Brian Yuliarto

doi:10.3390/s20174891

journal article Open Access Aug 29, 2020

Metal-Organic-Framework FeBDC-Derived Fe3O4 for Non-Enzymatic Electrochemical Detection of Glucose

Syauqi Abdurrahman Abrori

Ni Luh Wulan Septiani

Nugraha Isa Anshori

Suyatman Veinardi Suendo Brian Yuliarto

Sensors Vol. 20 No. 17 pp. 4891 · MDPI AG

View at Publisher Save 10.3390/s20174891

Abstract

Present-day science indicates that developing sensors with excellent sensitivity and selectivity for detecting early signs of diseases is highly desirable. Electrochemical sensors offer a method for detecting diseases that are simpler, faster, and more accurate than conventional laboratory analysis methods. Primarily, exploiting non-noble-metal nanomaterials with excellent conductivity and large surface area is still an area of active research due to its highly sensitive and selective catalysts for electrochemical detection in enzyme-free sensors. In this research, we successfully fabricate Metal-Organic Framework (MOF) FeBDC-derived Fe3O4 for non-enzymatic electrochemical detection of glucose. FeBDC synthesis was carried out using the solvothermal method. FeCl2.4H2O and Benzene-1,4-dicarboxylic acid (H2BDC) are used as precursors to form FeBDC. The materials were further characterized utilizing X-ray Powder Diffraction (XRD), Scanning Electron Microscopy (SEM), and Fourier-Transform Infrared Spectroscopy (FTIR). The resulting MOF yields good crystallinity and micro-rod like morphology. Electrochemical properties were tested using Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) with a 0.1 M of Phosphate Buffer Saline (PBS pH 7.4) solution as the supporting electrolyte. The measurement results show the reduction and oxidation peaks in the CV curve of FeBDC, as well as Fe3O4. Pyrolysis of FeBDC to Fe3O4 increases the peak of oxidation and reduction currents. The Fe3O4 sample obtained has a sensitivity of 4.67 µA mM−1.cm−2, a linear range between 0.0 to 9.0 mM, and a glucose detection limit of 15.70 µM.

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Published: Aug 29, 2020
Vol/Issue: 20(17)
Pages: 4891
License: View

Authors

S

Syauqi Abdurrahman Abrori

Advanced Functional Materials Laboratory, Engineering Physics Department, Faculty of Industrial Technology, Bandung Institute of Technology, Bandung 40132, Indonesia

N

Ni Luh Wulan Septiani

Advanced Functional Materials Laboratory, Engineering Physics Department, Faculty of Industrial Technology, Bandung Institute of Technology, Bandung 40132, Indonesia

N

Nugraha

Advanced Functional Materials Laboratory, Engineering Physics Department, Faculty of Industrial Technology, Bandung Institute of Technology, Bandung 40132, Indonesia; Research Center for Nanosciences and Nanotechnology (RCNN), Bandung Institute of Technology, Bandung 40132, Indonesia

I

Isa Anshori

Research Center for Nanosciences and Nanotechnology (RCNN), Bandung Institute of Technology, Bandung 40132, Indonesia; Lab-on-Chip Group, Biomedical Engineering Department, Bandung Institute of Technology, Bandung 40132, Indonesia

S

Suyatman

Advanced Functional Materials Laboratory, Engineering Physics Department, Faculty of Industrial Technology, Bandung Institute of Technology, Bandung 40132, Indonesia

V

Veinardi Suendo

Research Center for Nanosciences and Nanotechnology (RCNN), Bandung Institute of Technology, Bandung 40132, Indonesia; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, Bandung 40132, Indonesia

B

Brian Yuliarto

Advanced Functional Materials Laboratory, Engineering Physics Department, Faculty of Industrial Technology, Bandung Institute of Technology, Bandung 40132, Indonesia; Research Center for Nanosciences and Nanotechnology (RCNN), Bandung Institute of Technology, Bandung 40132, Indonesia

Cite This Article

Syauqi Abdurrahman Abrori, Ni Luh Wulan Septiani, Nugraha, et al. (2020). Metal-Organic-Framework FeBDC-Derived Fe3O4 for Non-Enzymatic Electrochemical Detection of Glucose. Sensors, 20(17), 4891. https://doi.org/10.3390/s20174891

Metal-Organic-Framework FeBDC-Derived Fe3O4 for Non-Enzymatic Electrochemical Detection of Glucose

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