journal article Open Access Jul 22, 2022

Effect of Pyrolysis Temperature on Removal Efficiency and Mechanisms of Hg(II), Cd(II), and Pb (II) by Maize Straw Biochar

Sustainability Vol. 14 No. 15 pp. 9022 · MDPI AG
View at Publisher Save 10.3390/su14159022
Abstract
Pyrolysis temperature significantly affects the properties of biochar, which in turn can affect the removal of heavy metal ions and the underlying mechanism. In this work, biochars from the pyrolysis of maize straw at 300, 400, and 500 °C (BC300, BC400, and BC500, respectively) and wheat straw at 400 °C (WBC400) were investigated. The influence of production temperature on the adsorption of Hg2+, Cd2+, and Pb2+ by maize straw biochar was investigated by the characterization of the biochars and by adsorption tests. The adsorption capacities of maize and wheat straw biochar were compared in an adsorption experiment. Biochar BC400 showed the best physical and chemical properties and had the largest number of surface functional groups. The pseudo-second-order kinetic model was more suitable for describing the adsorption behavior of metal ions to biochar. The Langmuir model better fit the experimental data. Biochar BC400 had a higher adsorption speed and a stronger adsorption capacity than WBC400. The sorption of Pb2+ and Hg2+ to maize straw biochar followed the mechanisms of surface precipitation of carbonates and phosphates and complexation with oxygenated functional groups and delocalized π electrons. The adsorption mechanism for Cd2+ was similar to those of Hg2+ and Pb2+, but precipitation mainly occurred through the formation of phosphate. In the multi-heavy-metal system, the adsorption of Cd2+ by BC400 was inhibited by Pb2+ and Hg2+. In summary, BC400 biochar was most suitable for the adsorption effect of heavy metals in aqueous solution.
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Published
Jul 22, 2022
Vol/Issue
14(15)
Pages
9022
License
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Authors
Funding
National Natural Science Foundation of China Award: 2008085MD107
National Key R&D Program of China Award: 2008085MD107
Natural Science Foundation of Anhui Province Award: 2008085MD107
Key R&D Program of Anhui Province Award: 2008085MD107
Cite This Article
Xiaohang Hu, Ruigang Zhang, Bing Xia, et al. (2022). Effect of Pyrolysis Temperature on Removal Efficiency and Mechanisms of Hg(II), Cd(II), and Pb (II) by Maize Straw Biochar. Sustainability, 14(15), 9022. https://doi.org/10.3390/su14159022
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