Atomic Force Microscopy Study of the Adsorption of Surfactant Corrosion Inhibitor Films

Yao Xiong; Bruce Brown; Brian Kinsella; Srdjan Nešić; Alain Pailleret

doi:10.5006/0915

journal article Oct 01, 2013

Atomic Force Microscopy Study of the Adsorption of Surfactant Corrosion Inhibitor Films

Yao Xiong

Bruce Brown Brian Kinsella Srdjan Nešić Alain Pailleret

Corrosion Vol. 70 No. 3 pp. 247-260 · Association for Materials Protection and Performance (AMPP)

View at Publisher Save 10.5006/0915

Abstract

The properties of an adsorbed corrosion inhibitor—tall oil fatty acid (TOFA) imidazolium chloride—on mica, gold, and X65 steel were studied using in situ atomic force microscopy (AFM). Topography images and thickness measurements show that the structure of inhibitor film changes from monolayer to bi-layer as inhibitor concentration exceeds its critical micelle concentration (CMC). Further kinetic study indicates that the developing of a full film took about 6 h. Quantitative force measurements were performed to evaluate the forces associated with adsorption of inhibitor films. Results show that the mechanical stress needed to physically remove adsorbed inhibitor molecules is of the order of MPa.

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Details

Published: Oct 01, 2013
Vol/Issue: 70(3)
Pages: 247-260

Authors

Y

Yao Xiong

Reproductive Medicine Center, Zhongnan Hospital Wuhan University Wuhan Hubei China

Cite This Article

Yao Xiong, Bruce Brown, Brian Kinsella, et al. (2013). Atomic Force Microscopy Study of the Adsorption of Surfactant Corrosion Inhibitor Films. Corrosion, 70(3), 247-260. https://doi.org/10.5006/0915

Atomic Force Microscopy Study of the Adsorption of Surfactant Corrosion Inhibitor Films

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