Passivity Breakdown of Copper in Borate Buffer Solutions Containing Cl−, SO42−, and NO3−

Yuting Zhou; Danbin Jia; Feixiong Mao; Jingkun Yu; Edouard Asselin

doi:10.5006/4083

journal article Jul 09, 2022

Passivity Breakdown of Copper in Borate Buffer Solutions Containing Cl−, SO42−, and NO3−

Yuting Zhou

Danbin Jia Feixiong Mao Jingkun Yu Edouard Asselin

Corrosion Vol. 78 No. 9 pp. 865-875 · Association for Materials Protection and Performance (AMPP)

View at Publisher Save 10.5006/4083

Abstract

The effects of Cl−, , and on the corrosion of copper in slightly alkaline, deaerated borate buffer solutions (BBS) were analyzed by potentiodynamic polarization, in situ surface-enhanced Raman spectroscopy, electrochemical impedance spectroscopy, scanning electron microscopy, and confocal microscope. Results showed that all three ions significantly affected the corrosion of copper in BBS, leading to a decrease in the breakdown potential for copper, thereby promoting passivity breakdown. The adsorption of Cl−, , and on the copper oxide film surface was detected, forming corrosion products, atacamite, brochantite, and gerhardtite, respectively. The passivity breakdown occurred at a lower potential for -containing solutions than for those with the other ions. The most severe corrosion morphology was obtained in -containing solutions, and large-scale pits with deep depths were distributed on the copper surface after passivity breakdown. In comparison, small pits and laterally growing pits and/or local rupture of the passive film occurred on the copper surface in the solution containing Cl− or after passivity breakdown.

Topics

No keywords indexed for this article. Browse by subject →

References

56

[1]

Ha Electrochim. Acta (2011) 10.1016/j.electacta.2011.04.008

[2]

Huang Corros. Sci. (2011) 10.1016/j.corsci.2011.04.017

[3]

Jakupi J. Nucl. Mater. (2015) 10.1016/j.jnucmat.2015.07.001

[4]

Procaccini Appl. Surf. Sci. (2013) 10.1016/j.apsusc.2012.12.050

[5]

Kunze Corros. Sci. (2004) 10.1016/s0010-938x(03)00140-9

[6]

Babić J. Electrochem. Soc. (2001) 10.1149/1.1354608

[7]

Díez-Pérez Curr. Opin. Solid State Mater. Sci. (2006) 10.1016/j.cossms.2007.01.002

[8]

Kinetics of passivation and pitting corrosion of polycrystalline copper in borate buffer solutions containing sodium chloride

M.R.G. de Chialvo, R.C. Salvarezza, D. Vasquez Moll et al.

Electrochimica Acta 1985 10.1016/0013-4686(85)80012-8

[9]

Drogowska Surf. Coat. Technol. (1988) 10.1016/0257-8972(88)90096-5

[10]

Ma Corros. Sci. (2015) 10.1016/j.corsci.2014.11.028

[11]

Martino J. Electrochem. Soc. (2019) 10.1149/2.0321902jes

[12]

Ibrahim Corros. Sci. (2018) 10.1016/j.corsci.2018.05.024

[13]

Chen Corros. Sci. (2018) 10.1016/j.corsci.2017.11.025

[14]

Martino Corros. Eng. Sci. Technol. (2017) 10.1080/1478422x.2017.1297575

[15]

Chen Corros. Sci. (2017) 10.1016/j.corsci.2016.10.024

[16]

Kursten Corros. Eng. Sci. Technol. (2011) 10.1179/1743278210y.0000000022

[17]

Kong Electrochim. Acta (2018) 10.1016/j.electacta.2018.10.004

[18]

Christy J. Appl. Electrochem. (2004) 10.1023/b:jach.0000009923.35223.f8

[19]

King "Microbially Influenced Corrosion of Copper Nuclear Fuel Waste Containers in a Canadian Disposal Vault" (1996)

[20]

Rahmouni Electrochim. Acta (2007) 10.1016/j.electacta.2006.12.079

[21]

Electrochemical corrosion of unalloyed copper in chloride media––a critical review

G. Kear, B.D. Barker, F.C. Walsh

Corrosion Science 2004 10.1016/s0010-938x(02)00257-3

[22]

King "Corrosion of Copper in Alkaline Chloride Environments" (2002)

[23]

Lee J. Electrochem. Soc. (1986) 10.1149/1.2108335

[24]

Meng Anal. Chem. (2015) 10.1021/acs.analchem.5b00052

[25]

Zhao Anal. Chem. (2013) 10.1021/ac4016769

[26]

Brown J. Electroanal. Chem. (1996) 10.1016/0022-0728(95)04400-0

[27]

Mankowski Corros. Sci. (1997) 10.1016/s0010-938x(96)00100-x

[28]

Duthil Corros. Sci. (1996) 10.1016/s0010-938x(96)88250-3

[29]

Ha J. Electrochem. Soc. (2012) 10.1149/2.045212jes

[30]

Pullin J. Environ. Chem. Eng. (2017) 10.1016/j.jece.2017.01.038

[31]

Khalil Chem. Eng. J. (2016) 10.1016/j.cej.2015.11.038

[32]

Edwards J. Am. Water Works Assoc. (1994) 10.1002/j.1551-8833.1994.tb06287.x

[33]

Edwards Corrosion (1994) 10.5006/1.3294345

[34]

Prokopec J. Mol. Struct. (2011) 10.1016/j.molstruc.2010.11.019

[35]

Youda Corros. Sci. (1988) 10.1016/0010-938x(88)90010-8

[36]

Hope Spectrochim. Acta A: Mol. Spectrosc. (1994) 10.1016/0584-8539(94)80214-9

[37]

Silva J. Electrochem. Soc. (2018) 10.1149/2.0841807jes

[38]

El-Taib Heakal Corros. Sci. (2011) 10.1016/j.corsci.2010.11.040

[39]

Yang Electrochim. Acta (2007) 10.1016/j.electacta.2006.07.052

[40]

Macdonald Electrochim. Acta (2011) 10.1016/j.electacta.2010.11.005

[41]

The Point Defect Model for the Passive State

Digby D. Macdonald

Journal of The Electrochemical Society 1992 10.1149/1.2069096

[42]

Pitting Corrosion of Metals: A Review of the Critical Factors

G. S. Frankel

Journal of The Electrochemical Society 1998 10.1149/1.1838615

[43]

Wei Corros. Sci. (2018) 10.1016/j.corsci.2018.02.057

[44]

Yi J. Electroanal. Chem. (2018) 10.1016/j.jelechem.2017.12.028

[45]

Sato Corrosion (1989) 10.5006/1.3582030

[46]

Kosec Corros. Sci. (2015) 10.1016/j.corsci.2014.10.017

[47]

Raman investigation of artificial patinas on recent bronze – Part I: climatic chamber exposure

Polonca Ropret, Tadeja Kosec

Journal of Raman Spectroscopy 2012 10.1002/jrs.4068

[48]

Hayez Analyst (2005) 10.1039/b419080g

[49]

Kosec J. Raman Spectrosc. (2012) 10.1002/jrs.4124

[50]

Showing 50 of 56 references

Metrics

1

Citations

56

References

Details

Published: Jul 09, 2022
Vol/Issue: 78(9)
Pages: 865-875

Authors

Y

Yuting Zhou

*School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China.; ***Department of Materials Engineering, The University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada.

D

Danbin Jia

*School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China.

F

Feixiong Mao

**Ningbo Key Laboratory of Marine Protection Materials, Ningbo Institute of Materials, Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.

J

Jingkun Yu

*School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China.

E

Edouard Asselin

***Department of Materials Engineering, The University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada.

Cite This Article

Yuting Zhou, Danbin Jia, Feixiong Mao, et al. (2022). Passivity Breakdown of Copper in Borate Buffer Solutions Containing Cl−, SO42−, and NO3−. Corrosion, 78(9), 865-875. https://doi.org/10.5006/4083

Passivity Breakdown of Copper in Borate Buffer Solutions Containing Cl−, SO42−, and NO3−

You May Also Like