Balancing Partial Ionic and Electronic Transport for Optimized Cathode Utilization of High‐Voltage LiMn2O4/Li3InCl6 Solid‐State Batteries

Theodoor A. Hendriks; Martin A. Lange; Ellen M. Kiens; Christoph Baeumer; Wolfgang G. Zeier

doi:10.1002/batt.202200544

journal article Open Access Feb 08, 2023

Balancing Partial Ionic and Electronic Transport for Optimized Cathode Utilization of High‐Voltage LiMn2O4/Li3InCl6 Solid‐State Batteries

Theodoor A. Hendriks

Martin A. Lange Ellen M. Kiens

Christoph Baeumer

Wolfgang G. Zeier

Batteries & Supercaps Vol. 6 No. 4 · Wiley

View at Publisher Save 10.1002/batt.202200544

Abstract

AbstractTheir suggested stability towards high‐voltage cathode materials makes halide‐based solid electrolytes currently an interesting class of ionic conductors for solid‐state batteries. Especially the LiMn2O4 spinel cathode active material is of interest due to its slightly higher nominal voltage and more resilience to overcharging compared to LiCoO2 and LiNixMnyCozO2 cathodes. Typically, a standard ratio of active material to solid electrolyte is used in composites for solid‐state batteries. However, for ideal transport properties, and thus to achieve balanced and optimal partial‐conductivities, this ratio needs to be re‐optimized each time the material basis is changed. In this work, we show transport in the composite measured through both DC polarization as well as transmission line modeling of the impedance spectra. By balancing the partial transport parameters of the composite, an optimum capacity of the solid‐state batteries is achieved. This work shows characterization and optimization of transport is required for unlocking the full potential of solid‐state batteries.

Topics

No keywords indexed for this article. Browse by subject →

References

53

[1]

A solid future for battery development

Jürgen Janek, Wolfgang G. Zeier

Nature Energy 10.1038/nenergy.2016.141

[2]

Lithium battery chemistries enabled by solid-state electrolytes

Arumugam Manthiram, Xiaodong Yu, Shaofei Wang

Nature Reviews Materials 10.1038/natrevmats.2016.103

[3]

10.1038/s41560-020-0565-1

[4]

High-power all-solid-state batteries using sulfide superionic conductors

Yuki Kato, Satoshi Hori, Toshiya Saito et al.

Nature Energy 10.1038/nenergy.2016.30

[5]

10.1088/2516-1083/ab73dd

[6]

10.1002/ijch.201400112

[7]

10.1002/aenm.202003369

[8]

10.1016/j.ssi.2010.10.001

[9]

10.1021/ja3110895

[10]

Evidence for a Solid-Electrolyte Inductive Effect in the Superionic Conductor Li 10 Ge 1– x Sn x P 2 S 12

Sean P. Culver, Alexander G. Squires, Nicolò Minafra et al.

Journal of the American Chemical Society 10.1021/jacs.0c10735

[11]

10.1021/acsami.7b01137

[12]

10.1002/aesr.202000077

[13]

10.1021/acs.chemmater.7b00931

[14]

10.1038/srep02261

[15]

Multi-Scale Mechanical Behavior of the Li3PS4 Solid-Phase Electrolyte

Lauryn L. Baranowski, Chelsea M. Heveran, Virginia L. Ferguson et al.

ACS Applied Materials & Interfaces 10.1021/acsami.6b06612

[16]

10.1021/acs.chemmater.9b00770

[17]

10.1149/1945-7111/abf8d7

[18]

10.1021/acs.chemmater.6b04990

[19]

10.1021/acsaem.1c02187

[20]

Wang C. Sci. Adv. (2021)

[21]

10.1021/acs.chemmater.0c04660

[22]

10.1002/aenm.201900626

[23]

10.1021/acs.chemmater.1c01123

[24]

10.1021/acs.chemmater.5b04940

[25]

Solid Halide Electrolytes with High Lithium‐Ion Conductivity for Application in 4 V Class Bulk‐Type All‐Solid‐State Batteries

Tetsuya Asano, Akihiro Sakai, Satoru Ouchi et al.

Advanced Materials 10.1002/adma.201803075

[26]

10.1149/1945-7111/ac50df

[27]

10.1002/anie.201901938

[28]

10.1002/ange.201901938

[29]

10.1002/anie.201909805

[30]

10.1002/ange.201909805

[31]

10.1016/s0079-6786(97)81003-5

[32]

10.1021/nl404430e

[33]

Spinel LiNi0.5Mn1.5O4 and its derivatives as cathodes for high-voltage Li-ion batteries

G. Q. Liu, L. Wen, Y. M. Liu

Journal of Solid State Electrochemistry 10.1007/s10008-010-1061-5

[34]

10.1021/acs.nanolett.2c02426

[35]

10.1021/acsenergylett.2c01397

[36]

10.1039/c0jm01090a

[37]

10.1002/batt.202000194

[38]

10.33774/chemrxiv-2021-vwnpt-v2

[39]

10.1021/accountsmr.1c00116

[40]

10.1021/acs.accounts.0c00874

[41]

10.1021/acs.chemmater.1c00555

[42]

10.1002/anie.202015238

[43]

10.1002/ange.202015238

[44]

Rosenbach C. Adv. Energy Mater. (2022)

[45]

10.1002/aenm.201902881

[46]

10.1021/acsami.9b22788

[47]

10.1016/j.jpowsour.2018.05.095

[48]

10.1002/adfm.202010620

[49]

10.1021/acsami.2c06460

[50]

10.1039/b001708f

Showing 50 of 53 references

Cited By

41

Quantifying the Impact of Cathode Composite Mixing Quality on Active Mass Utilization and Reproducibility of Solid‐State Battery Cells

Maximilian Kissel, Marie Schosland · 2025

Advanced Energy Materials

Opportunities and Limitations of Partial Transport Quantification in All-Solid-State Composite Electrodes

Sebastian Puls, Lukas Ketter · 2025

ACS Electrochemistry

Metrics

41

Citations

53

References

Details

Published: Feb 08, 2023
Vol/Issue: 6(4)
License: View

Authors

T

Theodoor A. Hendriks

Helmholtz Institut Münster (IEK-12) Forschungszentrum Jülich Corrensstrasse 46 D-48149 Münster Germany

M

Martin A. Lange

Institute of Inorganic and Analytical Chemistry University of Münster Corrensstrasse 30 D-48149 Münster Germany

E

Ellen M. Kiens

MESA+Institute for Nanotechnology University of Twente P. O. Box 217 Enschede 7500 AE The Netherlands

C

Christoph Baeumer

MESA+Institute for Nanotechnology University of Twente P. O. Box 217 Enschede 7500 AE The Netherlands

W

Wolfgang G. Zeier

Helmholtz Institut Münster (IEK-12) Forschungszentrum Jülich Corrensstrasse 46 D-48149 Münster Germany; Institute of Inorganic and Analytical Chemistry University of Münster Corrensstrasse 30 D-48149 Münster Germany

Cite This Article

Theodoor A. Hendriks, Martin A. Lange, Ellen M. Kiens, et al. (2023). Balancing Partial Ionic and Electronic Transport for Optimized Cathode Utilization of High‐Voltage LiMn2O4/Li3InCl6 Solid‐State Batteries. Batteries & Supercaps, 6(4). https://doi.org/10.1002/batt.202200544

Balancing Partial Ionic and Electronic Transport for Optimized Cathode Utilization of High‐Voltage LiMn2O4/Li3InCl6 Solid‐State Batteries

You May Also Like