Comprehensive Insights into the Reactivity of Electrolytes Based on Sodium Ions

Gebrekidan Gebresilassie Eshetu; Sylvie Grugeon; Huikyong Kim; Sangsik Jeong; Liming Wu; Gregory Gachot; Stéphane Laruelle; Michel Armand; Stefano Passerini

doi:10.1002/cssc.201501605

journal article Feb 02, 2016

Comprehensive Insights into the Reactivity of Electrolytes Based on Sodium Ions

Gebrekidan Gebresilassie Eshetu

Sylvie Grugeon Huikyong Kim Sangsik Jeong Liming Wu Gregory Gachot Stéphane Laruelle Michel Armand

Stefano Passerini

ChemSusChem Vol. 9 No. 5 pp. 462-471 · Wiley

View at Publisher Save 10.1002/cssc.201501605

Abstract

AbstractWe report a systematic investigation of Na‐based electrolytes that comprise various NaX [X=hexafluorophosphate (PF6), perchlorate (ClO4), bis(trifluoromethanesulfonyl)imide (TFSI), fluorosulfonyl‐(trifluoromethanesulfonyl)imide (FTFSI), and bis(fluorosulfonyl)imide (FSI)] salts and solvent mixtures [ethylene carbonate (EC)/dimethyl carbonate (DMC), EC/diethyl carbonate (DEC), and EC/propylene carbonate (PC)] with respect to the Al current collector stability, formation of soluble degradation compounds, reactivity towards sodiated hard carbon (Nax‐HC), and solid–electrolyte interphase (SEI) layer formation. Cyclic voltammetry demonstrates that the stability of Al is highly influenced by the nature of the anions, solvents, and additives. GC–MS analysis reveals that the formation of SEI telltales depends on the nature of the linear alkyl carbonates and the battery chemistry (Li+ vs. Na+). FTIR spectroscopy shows that double alkyl carbonates are the main components of the SEI layer on Nax‐HC. In the presence of Na salts, EC/DMC and EC/DEC presented a higher reactivity towards Nax‐HC than EC/PC. For a fixed solvent mixture, the onset temperature follows the sequence NaClO4<NaFTFSI<NaPF6<NaTFSI<NaFSI, and the total heat generated increases in the order NaFSI<NaTFSI<NaClO4<NaPF6<NaFTFSI.

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References

Details

Published: Feb 02, 2016
Vol/Issue: 9(5)
Pages: 462-471
License: View

Authors

G

Gebrekidan Gebresilassie Eshetu

Helmholtz Institute of Ulm (HIU) Helmholtz Str.11 89081 Ulm Germany; Karlsruhe Institute of Technology (KIT) P.O.Box 3640 76021 Karlsruhe Germany

S

Sylvie Grugeon

Laboratoire de Réactivité et Chimie des Solide (LRCS) CNRS UMR 7314 Université de Picardie Jules Verne 33 rue Saint Leu 80039 Amiens France; Réseau sur le Stockage Electrochimique de l'Energie, CNRS RS2E FR3459 France

H

Huikyong Kim

Laboratoire de Réactivité et Chimie des Solide (LRCS) CNRS UMR 7314 Université de Picardie Jules Verne 33 rue Saint Leu 80039 Amiens France; Renault, DEA-IREB, Renault, Technocentre 1 avenue du Golf 78084 Guyancourt France

S

Sangsik Jeong

Helmholtz Institute of Ulm (HIU) Helmholtz Str.11 89081 Ulm Germany; Karlsruhe Institute of Technology (KIT) P.O.Box 3640 76021 Karlsruhe Germany

L

Liming Wu

Helmholtz Institute of Ulm (HIU) Helmholtz Str.11 89081 Ulm Germany; Karlsruhe Institute of Technology (KIT) P.O.Box 3640 76021 Karlsruhe Germany

G

Gregory Gachot

Laboratoire de Réactivité et Chimie des Solide (LRCS) CNRS UMR 7314 Université de Picardie Jules Verne 33 rue Saint Leu 80039 Amiens France; Réseau sur le Stockage Electrochimique de l'Energie, CNRS RS2E FR3459 France

S

Stéphane Laruelle

Laboratoire de Réactivité et Chimie des Solide (LRCS) CNRS UMR 7314 Université de Picardie Jules Verne 33 rue Saint Leu 80039 Amiens France; Réseau sur le Stockage Electrochimique de l'Energie, CNRS RS2E FR3459 France

M

Michel Armand

CIC Energigune, Parque Tecnologico de Alava Albert Einstein 48, ED. CIC 01510 Minano Spain

S

Stefano Passerini

Helmholtz Institute of Ulm (HIU) Helmholtz Str.11 89081 Ulm Germany; Karlsruhe Institute of Technology (KIT) P.O.Box 3640 76021 Karlsruhe Germany

Cite This Article

Gebrekidan Gebresilassie Eshetu, Sylvie Grugeon, Huikyong Kim, et al. (2016). Comprehensive Insights into the Reactivity of Electrolytes Based on Sodium Ions. ChemSusChem, 9(5), 462-471. https://doi.org/10.1002/cssc.201501605

Comprehensive Insights into the Reactivity of Electrolytes Based on Sodium Ions

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