One‐Step Lignocellulose Fractionation by using 2,5‐Furandicarboxylic Acid as a Biogenic and Recyclable Catalyst

Dennis Weidener; Holger Klose; Walter Leitner; Ulrich Schurr; Björn Usadel; Pablo Domínguez de María; Philipp M. Grande

doi:10.1002/cssc.201800653

journal article Jun 19, 2018

One‐Step Lignocellulose Fractionation by using 2,5‐Furandicarboxylic Acid as a Biogenic and Recyclable Catalyst

Dennis Weidener Holger Klose

Walter Leitner

Ulrich Schurr

Björn Usadel

Pablo Domínguez de María

Philipp M. Grande

ChemSusChem Vol. 11 No. 13 pp. 2051-2056 · Wiley

View at Publisher Save 10.1002/cssc.201800653

Abstract

AbstractTo develop novel biorefinery concepts, the use of bio‐based catalysts and solvents must be aligned with the principles of green chemistry. In this context, biogenic 2,5‐furandicarboxylic acid (FDCA) is a very promising yet underused molecule with high potential for application as an acid catalyst, combining feasibility and sustainability with efficient and straightforward recovery. In this study, FDCA was evaluated as a catalyst in the recently developed OrganoCat pretreatment, a biphasic lignocellulose fractionation system. The catalyst was investigated for the efficient fractionation of the three main components—lignin, cellulose and noncellulosic sugars—with particular focus on the lignin quality, on the effect on enzymatic hydrolysis of the cellulosic residue, and on the noncellulosic sugar extraction. To address recovery of FDCA from the OrganoCat system, a method was developed, leading to the recovery of >97 % of FDCA with a spectroscopic purity of >99 %, maintaining full activity in consecutive runs.

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References

Details

Published: Jun 19, 2018
Vol/Issue: 11(13)
Pages: 2051-2056
License: View

Authors

D

Dennis Weidener

Institut für Technische und Makromolekulare Chemie (ITMC) RWTH Aachen University Worringerweg 1–2 52074 Aachen Germany; Bioeconomy Science Center (BioSC) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany

H

Holger Klose

Institut für Bio- und Geowissenschaften, Pflanzenwissenschaften (IBG-2) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany; Bioeconomy Science Center (BioSC) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany; Institute for Biology I RWTH Aachen University Worringer Weg 3 52074 Aachen Germany

W

Walter Leitner

Institut für Technische und Makromolekulare Chemie (ITMC) RWTH Aachen University Worringerweg 1–2 52074 Aachen Germany; Max-Planck-Institut für Chemische Energiekonversion Stiftstraße 34–36 45470 Mülheim an der Ruhr Germany

U

Ulrich Schurr

Institut für Bio- und Geowissenschaften, Pflanzenwissenschaften (IBG-2) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany; Bioeconomy Science Center (BioSC) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany

B

Björn Usadel

Institut für Bio- und Geowissenschaften, Pflanzenwissenschaften (IBG-2) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany; Bioeconomy Science Center (BioSC) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany; Institute for Biology I RWTH Aachen University Worringer Weg 3 52074 Aachen Germany

P

Pablo Domínguez de María

Sustainable Momentum, SL Av. Ansite 3, 4–6 35011 Las Palmas de Gran Canaria, Canary Islands Spain

P

Philipp M. Grande

Institut für Bio- und Geowissenschaften, Pflanzenwissenschaften (IBG-2) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany; Bioeconomy Science Center (BioSC) Forschungszentrum Jülich Wilhelm Johnen Straße 52425 Jülich Germany

Cite This Article

Dennis Weidener, Holger Klose, Walter Leitner, et al. (2018). One‐Step Lignocellulose Fractionation by using 2,5‐Furandicarboxylic Acid as a Biogenic and Recyclable Catalyst. ChemSusChem, 11(13), 2051-2056. https://doi.org/10.1002/cssc.201800653

One‐Step Lignocellulose Fractionation by using 2,5‐Furandicarboxylic Acid as a Biogenic and Recyclable Catalyst

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