Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid over Holey 2 D Mn2O3 Nanoflakes from a Mn‐based MOF

Liwei Bao; Fang‐Zhou Sun; Guo‐Ying Zhang; Tengtao Hu

doi:10.1002/cssc.201903018

journal article Dec 16, 2019

Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid over Holey 2 D Mn2O3 Nanoflakes from a Mn‐based MOF

Liwei Bao Fang‐Zhou Sun Guo‐Ying Zhang Tengtao Hu

ChemSusChem Vol. 13 No. 3 pp. 548-555 · Wiley

View at Publisher Save 10.1002/cssc.201903018

Abstract

AbstractThe aerobic oxidation of 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA), a promising renewable monomer to produce bio‐based polymers such as polyethylene furanoate (PEF), has recently emerged as the subject of increasing interest. Here, holey 2 D Mn2O3 nanoflakes were obtained by a facile thermal treatment of a Mn‐based metal–organic framework (MOF) precursor. The structural and morphological properties of the nanoflakes were characterized by powder XRD, FTIR, SEM and TEM to explore the formation process. It was inferred that the linker loss in the MOF precursor and the oxidation of the Mn cation induced by the heat‐treatment in air were responsible for the formation of holey 2 D Mn2O3 nanoflakes. The specific morphology and redox cycle of the Mn cation on the surface endowed the synthesized nanoflakes with promising performance on the selective oxidation. The obtained nanoflakes calcined at 400 °C (M400) afforded over 99.5 % yield of FDCA at complete conversion of HMF, which is superior to the catalytic activity of commercial Mn2O3 and activated MnO2. To our knowledge, Mn2O3 exhibiting such a high performance on the aerobic oxidation of HMF to FDCA has not yet been reported. Based on the investigation of the experimental parameters, a plausible reaction mechanism was proposed.

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Metrics

90

Citations

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References

Details

Published: Dec 16, 2019
Vol/Issue: 13(3)
Pages: 548-555
License: View

Authors

L

Liwei Bao

School of Materials Science and Engineering Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry National Institute for Advanced Materials Nankai University Tianjin 300350 P.R. China

F

Fang‐Zhou Sun

School of Materials Science and Engineering Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry National Institute for Advanced Materials Nankai University Tianjin 300350 P.R. China

G

Guo‐Ying Zhang

Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry (Ministry of Education) College of Chemistry Tianjin Normal University Tianjin 300387 P.R. China; Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals Shandong Normal University Jinan 250014 P.R. China

T

Tengtao Hu

School of Materials Science and Engineering Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry National Institute for Advanced Materials Nankai University Tianjin 300350 P.R. China; Tianjin Key Lab for Rare Earth Materials and Applications Key Laboratory of Advanced Energy Material Chemistry (Ministry of Education) Nankai University Tianjin 300071 P.R. China

Funding

National Natural Science Foundation of China Award: 21673120

Cite This Article

Liwei Bao, Fang‐Zhou Sun, Guo‐Ying Zhang, et al. (2019). Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid over Holey 2 D Mn2O3 Nanoflakes from a Mn‐based MOF. ChemSusChem, 13(3), 548-555. https://doi.org/10.1002/cssc.201903018

Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid over Holey 2 D Mn2O3 Nanoflakes from a Mn‐based MOF

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