Understanding the Role of Base Species on Reversed Cu Catalyst in Ring Opening of Furan Compounds to 1, 2‐Pentanediol

Huixiang Li; Xuezhong Nie; Hong Du; Yang Zhao; Junju Mu; Z. Conrad Zhang

doi:10.1002/cssc.202300880

journal article Oct 30, 2023

Understanding the Role of Base Species on Reversed Cu Catalyst in Ring Opening of Furan Compounds to 1, 2‐Pentanediol

Huixiang Li Xuezhong Nie Hong Du

Yang Zhao

Junju Mu

Z. Conrad Zhang

ChemSusChem Vol. 17 No. 1 · Wiley

View at Publisher Save 10.1002/cssc.202300880

Abstract

AbstractThe hydrogenation of biomass‐derived furan compounds provides a sustainable pathway for the production of various valuable chemicals; product selectivity among multiple reaction pathways of furan compound hydrogenation is crucially dependent on catalytic sites; however controlling reaction pathways remains challenging due to the lack of identification and understanding of active sites. In this work we reveal the role of base sites in furfural selective hydrogenation through deliberately designed and synthesized reversed catalysts, basic metal oxides and hydroxide on Cu. It is demonstrated that base species greatly enhanced the selectivity of 1, 2‐pentanediol (1, 2‐PeD) from furfural, presenting a nearly fourfold increase of 1, 2‐PeD: methyl furan ratio over the Cu based reverse catalysts. A combination of infrared spectroscopy and DFT calculations demonstrates the strong interaction between the C−O−C bond in furan ring and the catalyst surface in preferentially parallel adsorption mode in the presence of base species on Cu, thus facilitating the activation of C−O−C bond to produce 1, 2‐PeD. This work provides a strategy of designing reversed catalyst to study the effect of promoters and reveals the role of base sites in the hydrogenation of biomass‐derived furan compounds to diols.

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Details

Published: Oct 30, 2023
Vol/Issue: 17(1)
License: View

Authors

H

Huixiang Li

National-local Joint Engineering Research Center of Biomass Refining and High-quality Utilization Changzhou University Changzhou 213164 China; Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 Liaoning China

X

Xuezhong Nie

Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 Liaoning China; University of Chinese Academy of Sciences 100049 Beijing China

H

Hong Du

Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 Liaoning China

Y

Yang Zhao

Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 Liaoning China

J

Junju Mu

Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 Liaoning China

Z

Z. Conrad Zhang

National-local Joint Engineering Research Center of Biomass Refining and High-quality Utilization Changzhou University Changzhou 213164 China; Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 Liaoning China

Funding

National Natural Science Foundation of China Award: 22202196

Cite This Article

Huixiang Li, Xuezhong Nie, Hong Du, et al. (2023). Understanding the Role of Base Species on Reversed Cu Catalyst in Ring Opening of Furan Compounds to 1, 2‐Pentanediol. ChemSusChem, 17(1). https://doi.org/10.1002/cssc.202300880

Understanding the Role of Base Species on Reversed Cu Catalyst in Ring Opening of Furan Compounds to 1, 2‐Pentanediol

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