Trace Iron‐Modified CeO₂‐Supported Core‐Shell CoO@Co Catalyst for Selective Conversion of Furfural to 1,5‐Pentanediol

Shenyu Wang; Junjie Zhang; Ying Zhang

doi:10.1002/cssc.202401938

journal article Nov 20, 2024

Trace Iron‐Modified CeO₂‐Supported Core‐Shell CoO@Co Catalyst for Selective Conversion of Furfural to 1,5‐Pentanediol

Shenyu Wang Junjie Zhang

Ying Zhang

ChemSusChem Vol. 18 No. 6 · Wiley

View at Publisher Save 10.1002/cssc.202401938

Abstract

AbstractIn the conversion of furfural using non‐noble metal catalysts, preferential cleavage of the C2−O bond followed by hydrogenation of the C=C bond facilitates selective access to valuable 1,5‐pentanediol (1,5‐PeD). Herein, we developed CeO₂ loaded core‐shell CoO@Co nanoparticle catalysts. Adjusting Co loading, Fe doping, and reduction temperature improved reaction efficiency. 7Co‐0.2Fe/CeO₂ catalysts reduced at 500 °C demonstrated optimal performance. 1,5‐PeD produced at 54.76 mmol/gCo/h, representing the top activity levels among the reported catalysts. H₂‐TPR, XRD, HAADF‐STEM, FT‐IR, XPS, and XANES were employed to investigate the catalyst structure‐activity relationship. Co2+ cleaves furan ring C−O bond, Co⁰ promotes double‐bond hydrogenation. The CoO@Co structure favors the desired 1,5‐PeD production route. Trace Fe species optimize the Co2+/Co⁰ ratio, enhance the substrate adsorption, and inhibit the furan ring saturation. These findings emphasize the importance of fine‐tuning catalyst structure and composition for selectivity improvement.

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References

Details

Published: Nov 20, 2024
Vol/Issue: 18(6)
License: View

Authors

S

Shenyu Wang

Department of Applied Chemistry Key Laboratory of Precision and Intelligent Chemistry University of Science and Technology of China Hefei, Anhui 230026 China

J

Junjie Zhang

Department of Applied Chemistry Key Laboratory of Precision and Intelligent Chemistry University of Science and Technology of China Hefei, Anhui 230026 China

Y

Ying Zhang

Department of Applied Chemistry Key Laboratory of Precision and Intelligent Chemistry University of Science and Technology of China Hefei, Anhui 230026 China

Funding

National Natural Science Foundation of China Award: No. 22378377

National Key Research and Development Program of China Award: 2022YFB4201804

Cite This Article

Shenyu Wang, Junjie Zhang, Ying Zhang (2024). Trace Iron‐Modified CeO₂‐Supported Core‐Shell CoO@Co Catalyst for Selective Conversion of Furfural to 1,5‐Pentanediol. ChemSusChem, 18(6). https://doi.org/10.1002/cssc.202401938

Trace Iron‐Modified CeO₂‐Supported Core‐Shell CoO@Co Catalyst for Selective Conversion of Furfural to 1,5‐Pentanediol

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