A comprehensive modeling study of hydrogen oxidation

Marcus Ó Conaire; Henry J. Curran; John M. Simmie; William J. Pitz; Charles K. Westbrook

doi:10.1002/kin.20036

journal article Aug 30, 2004

A comprehensive modeling study of hydrogen oxidation

Marcus Ó Conaire Henry J. Curran

John M. Simmie William J. Pitz Charles K. Westbrook

International Journal of Chemical Kinetics Vol. 36 No. 11 pp. 603-622 · Wiley

View at Publisher Save 10.1002/kin.20036

Abstract

AbstractA detailed kinetic mechanism has been developed to simulate the combustion of H2/O2 mixtures, over a wide range of temperatures, pressures, and equivalence ratios. Over the series of experiments numerically investigated, the temperature ranged from 298 to 2700 K, the pressure from 0.05 to 87 atm, and the equivalence ratios from 0.2 to 6.Ignition delay times, flame speeds, and species composition data provide for a stringent test of the chemical kinetic mechanism, all of which are simulated in the current study with varying success. A sensitivity analysis was carried out to determine which reactions were dominating the H2/O2 system at particular conditions of pressure, temperature, and fuel/oxygen/diluent ratios. Overall, good agreement was observed between the model and the wide range of experiments simulated. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 603–622, 2004

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Citations

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References

Details

Published: Aug 30, 2004
Vol/Issue: 36(11)
Pages: 603-622
License: View

Authors

Combustion Chemistry Centre National University of Ireland Galway Ireland

Cite This Article

Marcus Ó Conaire, Henry J. Curran, John M. Simmie, et al. (2004). A comprehensive modeling study of hydrogen oxidation. International Journal of Chemical Kinetics, 36(11), 603-622. https://doi.org/10.1002/kin.20036

A comprehensive modeling study of hydrogen oxidation

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