A zero-thermal-quenching phosphor

Xia, Z. & Liu, R.-S. Tunable blue-green color emission and energy transfer of Ca2Al3O6F:Ce3+, Tb3+ phosphors for near-UV white LEDs. J. Phys. Chem. C 116, 15604–15609 (2012). 10.1021/jp304722z

[4]

Lin, C. C. & Liu, R.-S. Advances in phosphors for light-emitting diodes. J. Phys. Chem. Lett. 2, 1268–1277 (2011). 10.1021/jz2002452

[5]

Daicho, H. et al. A novel phosphor for glareless white light-emitting diodes. Nat. Commun. 3, 1132 (2012). 10.1038/ncomms2138

[6]

Zhu, H. et al. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes. Nat. Commun. 5, 4312 (2014). 10.1038/ncomms5312

[7]

Muñoz, G. H., de la Cruz, C. L., Muñoz, A. F. & Rubio, J. O. High-temperature luminescence properties of Eu2+-activated alkali halide phosphor materials. J. Mater. Sci. Lett. 7, 1310–1312 (1988). 10.1007/bf00719967

[8]

Blasse, G. & Grabmaier, B. Luminescent Materials (Springer, 1994). 10.1007/978-3-642-79017-1

[9]

Dorenbos, P. Thermal quenching of Eu2+ 5d–4f luminescence in inorganic compounds. J. Phys. Condens. Matter 17, 8103–8111 (2005). 10.1088/0953-8984/17/50/027

[10]

Blasse, G. Thermal quenching of characteristic fluorescence. J. Chem. Phys. 51, 3529–3530 (1969). 10.1063/1.1672543

[11]

Takeda, T., Hirosaki, N., Funahshi, S. & Xie, R.-J. Narrow-band green-emitting phosphor Ba2LiSi7AlN12:Eu2+ with high thermal stability discovered by a single particle diagnosis approach. Chem. Mater. 27, 5892–5898 (2015). 10.1021/acs.chemmater.5b01464

[12]

Xie, R.-J. & Hirosaki, N. Silicon-based oxynitride and nitride phosphors for white LEDs—a review. Sci. Tech. Adv. Mater. 8, 588–600 (2007). 10.1016/j.stam.2007.08.005

[13]

Chen, L., Lin, C.-C., Yeh, C.-W. & Liu, R.-S. Light converting inorganic phosphors for white light-emitting diodes. Materials 3, 2172–2195 (2010). 10.3390/ma3032172

[14]

Bachmann, V. et al. Color point tuning for (Sr, Ca, Ba)Si2O2N2:Eu2+ for white light LEDs. Chem. Mater. 21, 316–325 (2009). 10.1021/cm802394w

[15]

Efficient and Color‐Tunable Oxyfluoride Solid Solution Phosphors for Solid‐State White Lighting

Won Bin Im, Nathan George, Joshua Kurzman et al.

Advanced Materials 2011 10.1002/adma.201003640

[16]

Im, W. B. et al. Sr2.975−xBaxCe0.025AlO4F: a highly efficient green-emitting oxyfluoride phosphor for solid state white lighting. Chem. Mater. 22, 2842–2849 (2010). 10.1021/cm100010z

[17]

Zhuang, J. et al. The improvement of moisture resistance and thermal stability of Ca3SiO4Cl2:Eu2+ phosphor coated with SiO2 . Appl. Surf. Sci. 257, 4350–4353 (2011). 10.1016/j.apsusc.2010.12.055

[18]

Lee, H. S. & Yoo, J. W. Yellow phosphors coated with TiO2 for the enhancement of photoluminescence and thermal stability. Appl. Surf. Sci. 257, 8355–8359 (2011). 10.1016/j.apsusc.2011.03.137

[19]

Nakanishi, T. & Tanabe, S. Preparation and luminescent properties of Eu2+-activated glass ceramic phosphor precipitated with β-Ca2SiO4 and Ca3Si2O7 . Phys. Status Solidi A 206, 919–922 (2009). 10.1002/pssa.200881326

[20]

Bykov, A. B. et al. Superionic conductors Li3M2(PO4)3 (M = Fe, Sc, Cr): Synthesis, structure and electrophysical properties. Solid State Ion. 38, 31–52 (1990). 10.1016/0167-2738(90)90442-t

[21]

de la Rochère, M. et al. NASICON type materials—Na3M2(PO4)3 (M = Sc, Cr, Fe): Na+-Na+ correlations and phase transitions. Solid State Ion. 9–10, 825–828 (1983). 10.1016/0167-2738(83)90096-6

[22]

Masui, T., Koyabu, K., Tamura, S. & Imanaka, N. Synthesis of a new NASICON-type blue luminescent material. J. Alloys Compd. 418, 73–76 (2006). 10.1016/j.jallcom.2005.08.097

[23]

Saradhi, M., Pralong, V., Varadaraju, U. & Raveau, B. Facile chemical insertion of lithium in Eu0.33Zr2(PO4)3—an elegant approach for tuning the photoluminescence properties. Chem. Mater. 21, 1793–1795 (2009). 10.1021/cm900309p

[24]

Delbecq, C. J., Marshall, S. A. & Susman, S. Evidence for a structural phase change in the fast-ion conductor Na3Sc2P3O12 . Solid State Ion. 1, 145–149 (1980). 10.1016/0167-2738(80)90029-6

[25]

Mundy, J., Shenoy, G. & Vashishta, P. Fast ion transport in solids: electrodes, and electrolytes Proc. Int. Conf. Fast Ion Transport in Solids, Electrodes, and Electrolytes (Elsevier North Holland, 1979).

[26]

Wickleder, M. S. Inorganic lanthanide compounds with complex anions. Chem. Rev. 102, 2011–2088 (2002). 10.1021/cr010308o

[27]

Sorokin, N. I. Na+-ion conductivity of double phosphate Na3Sc2(PO4)3 in the region of the β–γ transition. Phys. Solid State 56, 678–681 (2014). 10.1134/s1063783414040325

[28]

Collin, G., Comes, R., Boilot, J. & Colomban, P. Disorder of tetrahedra in Nasicon-type structure—I.: Na3Sc2(PO4)3: structures and ion–ion correlations. J. Phys. Chem. Solids 47, 843–854 (1986). 10.1016/0022-3697(86)90055-7

[29]

Winand, J. M., Rulmont, A. & Tarte, P. Ionic conductivity of the Na1+xMxIIIZr2−x(PO4)3 systems (M = Al, Ga, Cr, Fe, Sc, In, Y, Yb). J. Mater. Sci. 25, 4008–4013 (1990). 10.1007/bf00582473

[30]

Keen, D. A. Disordering phenomena in superionic conductors. J. Phys. Condens. Matter 14, R819–R857 (2002). 10.1088/0953-8984/14/32/201

[31]

Mazza, D. Modeling ionic conductivity in nasicon structures. J. Solid State Chem. 156, 154–160 (2001). 10.1006/jssc.2000.8975

[32]

Pan, Z., Lu, Y.-Y. & Liu, F. Sunlight-activated long-persistent luminescence in the near-infrared from Cr3+-doped zinc gallogermanates. Nat. Mater. 11, 58–63 (2012). 10.1038/nmat3173

[33]

Garlick, G. & Gibson, A. The electron trap mechanism of luminescence in sulphide and silicate phosphors. Proc. Phys. Soc. 60, 574–590 (1948). 10.1088/0959-5309/60/6/308

[34]

Van den Eeckhout, K., Smet, P. F. & Poelman, D. Persistent luminescence in Eu2+-doped compounds: a review. Materials 3, 2536–2566 (2010). 10.3390/ma3042536

[35]

Larson, A. C. & Von Dreele, R. B. General Structure Analysis System (GSAS) Los Alamos National Laboratory Report LAUR 86–748 (The Regents of the University of California, 1994).

[36]

Momma, K. & Izumi, F. VESTA: a three-dimensional visualization system for electronic and structural analysis. J. Appl. Crystallogr. 41, 653–658 (2008). 10.1107/s0021889808012016

[37]

Projector augmented-wave method

P. E. Blöchl

Physical Review B 1994 10.1103/physrevb.50.17953

[38]

Generalized Gradient Approximation Made Simple

John P. Perdew, Kieron Burke, Matthias Ernzerhof

Physical Review Letters 1996 10.1103/physrevlett.77.3865

[39]

Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169–11186 (1996). 10.1103/physrevb.54.11169

[40]

Monkhorst, H. J. & Pack, J. D. Special points for Brillouin-zone integrations. Phys. Rev. B 13, 5188–5192 (1976). 10.1103/physrevb.13.5188

Cited By

1,014

Temperature-dependent luminescence of isostructural [Eu(TPTZ)(NO3)3] and [Tb(TPTZ)(NO3)3] compounds: Insights into the ligand–lanthanide (5D0/5D4 levels) energy gap ΔE

Ch.J. Salas-Juárez, R. Aceves · 2026

Journal of Luminescence

Spectral tuning of K1-Na Al11O17: 0.06Eu2 + phosphors induced by crystal lattice engineering and its application in high color rendering full spectrum WLED

Zhihui Wang, Yingnan Dong · 2026

Journal of Alloys and Compounds

Chemical unit substitution at B/B′ site enables efficient red emission and high thermal stability in NaGdMgWO6:Eu3+ for white light-emitting diodes application

Zhichen Liu, Qiong Zhou · 2026

Materials Today Chemistry

Highly thermally stable La3SnGa5O14: Sm3+ orange-red phosphors for optical thermometers and fingerprint detection

Yixi Lu, Bin Cao · 2025

Ceramics International

On-Crystal Spectral Modulator from Polarized Propagation of Lanthanide-Titanium Nanoclusters

Feng Jiang, Lei Qin · 2025

Journal of the American Chemical So...

Non‐Stoichiometric Calcium Addition in Red‐Emitting CaSc2O4:Eu2+ Phosphor Toward Enhanced Photoluminescence Quantum Efficiency for LED Applications

Zhiyu Yang, Guangxiang Lu · 2025

Laser & Photonics Reviews

A Thermal Stable Multi‐Functional Cu+‐doped Glass for High‐Resolution X‐Ray Imaging and Full‐Spectra Lighting

Guanlin He, Lianjie Li · 2025

Laser & Photonics Reviews

Efficient and abnormal thermal quenching Sm3+ activated perovskites-type niobate phosphor for plant growth lamp and WLEDs

Zaifa Yang, Mingjing Ye · 2024

Ceramics International

Novel Y2(SO4)3:Eu3+ Phosphors with Anti-Thermal Quenching of Luminescence Due to Giant Negative Thermal Expansion

Andrey P. Shablinskii, Olga Yu. Shorets · 2024

Crystals

Synthesis Strategies for Rare Earth Activated Inorganic Phosphors: A Mini Review

Sitender Singh, Devender Singh · 2024

Applied Research

Integrating K+ into Eu and Tb doped GdCa4O(BO3)3: A dual study on photoluminescence and structure

Abeer S. Altowyan, U.H. Kaynar · 2024

Sensors and Actuators A: Physical

Dual-emission ultra-wideband phosphor applied to yellow light LED and temperature visualization

Qincan Ma, Jinyuan Zhang · 2024

Materials Today Chemistry

Laser-driven broadband near-infrared light source with watt-level output

Gaochao Liu, Weibin Chen · 2024

Nature Photonics

Synthesis and optical properties of highly efficient Na3KMg7(PO4)6:Eu2+ blue phosphor for full-spectrum white-light-emitting diodes: The role of Li2CO3 flux

Zihao Wang, Sisi Liang · 2024

Journal of Rare Earths

Energy‐Trapping Management in X‐Ray Storage Phosphors for Flexible 3D Imaging

Xinquan Zhou, Kai Han · 2023

Advanced Materials

Multi-sites energy transfer in Fe3+-doped KAl11O17 phosphor toward zero thermal quenching near-infrared luminescence

Gaochao Liu, Zhiguo Xia · 2023

Optics Letters

Interplay of Consecutive Energy Transfer and Negative Thermal Expansion Property for Achieving Superior Anti‐Thermal Quenching Luminescence

Forough Jahanbazi, Nicholas Dimakis · 2023

Advanced Optical Materials

Recent progress in Ce3+/Eu2+-activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure

Shuxin Wang, Zhen Song · 2023

Journal of Materials Chemistry C

Garnet-type far-red emitting Li6CaLa2Nb2O12: Mn4+, Bi3+ phosphor for full-spectrum white LED

Mengmeng Shang, Kangliang Peng · 2022

Journal of Luminescence

Adjusting the luminescence properties by the substitution of alkali metal ions in MGd9(SiO4)6O2:Dy3+: Preparation, DFT calculation and optical properties

Yuanyuan Zhang, Lefu Mei · 2022

Journal of Luminescence

Metrics

1,014

Citations

40

References

Details

Published: Feb 13, 2017
Vol/Issue: 16(5)
Pages: 543-550
License: View

Authors

Cite This Article

Yoon Hwa Kim, Paulraj Arunkumar, Bo Young Kim, et al. (2017). A zero-thermal-quenching phosphor. Nature Materials, 16(5), 543-550. https://doi.org/10.1038/nmat4843

A zero-thermal-quenching phosphor

You May Also Like