Multi-sites energy transfer in Fe3+-doped KAl11O17 phosphor toward zero thermal quenching near-infrared luminescence

Gaochao Liu; Zhiguo Xia

doi:10.1364/ol.481641

journal article Feb 28, 2023

Multi-sites energy transfer in Fe3+-doped KAl11O17 phosphor toward zero thermal quenching near-infrared luminescence

Gaochao Liu Zhiguo Xia

Optics Letters Vol. 48 No. 5 pp. 1296 · Optica Publishing Group

View at Publisher Save 10.1364/ol.481641

Abstract

Near-infrared (NIR) phosphor-converted light-emitting diodes (pc-LEDs) have demonstrated great potential for optoelectronic and biomedical applications, while the exploration of NIR phosphors with high thermal stability remains a challenge. Herein, we report an NIR phosphor KAl11O17:Fe3+ with zero thermal quenching (TQ) behavior up to 200°C. The asymmetrical broadband NIR emission with three sub-bands centered at 700, 770, and 800 nm is related to the superposition of different Fe3+ emission centers located in Al2O4, Al3O6, and Al4O6 sites of the KAl11O17 host, respectively. Temperature- and Fe3+ concentration-dependent emission spectra verify that the energy transfer (ET) between multiple Fe3+ emitters and the weak electron–phonon coupling (EPC) effect contribute to the thermally stable broadband NIR emission. The fabricated NIR pc-LED using optimized KAl11O17:Fe3+ phosphor exhibits great potential in information encryption applications.

Topics

No keywords indexed for this article. Browse by subject →

References

27

[1]

Qiao Nat. Commun. (2019) 10.1038/s41467-019-13293-0

[2]

A highly efficient and suitable spectral profile Cr3+-doped garnet near-infrared emitting phosphor for regulating photomorphogenesis of plants

Xikun Zou, Xiaojun Wang, Haoran Zhang et al.

Chemical Engineering Journal 2022 10.1016/j.cej.2021.132003

[3]

Jiang J. Rare Earths (2022) 10.1016/j.jre.2021.05.007

[4]

Wang Inorg. Chem. Front. (2022) 10.1039/d2qi00794k

[5]

Liu J. Phys. Chem. Lett. (2022) 10.1021/acs.jpclett.2c01143

[6]

Zhao Adv. Mater. (2018) 10.1002/adma.201802489

[7]

Zhuo Nat. Commun. (2018) 10.1038/s41467-018-06625-z

[8]

Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources

Zhenwei Jia, Chenxu Yuan, Yongfu Liu et al.

Light: Science & Applications 2020 10.1038/s41377-020-0326-8

[9]

A zero-thermal-quenching phosphor

Yoon Hwa Kim, Paulraj Arunkumar, Bo Young Kim et al.

Nature Materials 2017 10.1038/nmat4843

[10]

Blue LED-pumped intense short-wave infrared luminescence based on Cr3+-Yb3+-co-doped phosphors

Shihai Miao, Yanjie Liang, Chao Liang et al.

Light: Science & Applications 2022 10.1038/s41377-022-00816-6

[11]

Enhancing Near-Infrared Photoluminescence Intensity and Spectral Properties in Yb3+ Codoped LiScP2O7:Cr3+

Qiyue Shao, Shouyu Han, Chao Liang et al.

Chemistry of Materials 2020 10.1021/acs.chemmater.9b04934

[12]

Li Mater. Today Chem. (2022) 10.1016/j.mtchem.2021.100744

[13]

Efficient Ultra‐Broadband Ga 4 GeO 8 :Cr 3+ Phosphors with Tunable Peak Wavelengths from 835 to 980 nm for NIR pc‐LED Application

Lihong Yao, Qiyue Shao, Mengke Shi et al.

Advanced Optical Materials 2022 10.1002/adom.202102229

[14]

Review—Photoluminescence Properties of Cr3+-Activated Oxide Phosphors

Sadao Adachi

ECS Journal of Solid State Science and Technology 2021 10.1149/2162-8777/abdc01

[15]

Efficient broadband near-infrared phosphor Sr2ScSbO6:Cr3+ for solar-like lighting

Meng Zhao, Shengqiang Liu, Hao Cai et al.

Science China Materials 2022 10.1007/s40843-021-1785-6

[16]

Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis

Dongjie Liu, Guogang Li, Peipei Dang et al.

Light: Science & Applications 2022 10.1038/s41377-022-00803-x

[17]

Wu Chem. Eng. J. (2022) 10.1016/j.cej.2021.132225

[18]

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

R. D. Shannon

Acta Crystallographica Section A 1976 10.1107/s0567739476001551

[19]

Silva J. Alloys Compd. (2022) 10.1016/j.jallcom.2022.166959

[20]

Li Mater. Res. Bull. (2014) 10.1016/j.materresbull.2013.11.008

[21]

Zeng J. Lumin. (2021) 10.1016/j.jlumin.2020.117810

[22]

Lin Light: Sci. Appl. (2020) 10.1038/s41377-020-0258-3

[23]

Wang J. Phys. Chem. C (2020) 10.1021/acs.jpcc.9b09379

[24]

Liu Chem. Mater. (2022) 10.1021/acs.chemmater.1c04131

[25]

On the Absorption Spectra of Complex Ions II

Yukito Tanabe, Satoru Sugano

Journal of the Physical Society of Japan 1954 10.1143/jpsj.9.766

[26]

Song Laser Photonics Rev. (2021) 10.1002/lpor.202000410

[27]

Li Chem. Mater. (2022) 10.1021/acs.chemmater.2c02174

Cited By

46

Fe3+-doped broadband near-infrared phosphor with high quantum efficiency toward multifunctional pc-LEDs applications

Chengning Xie, Yunzhi Zhang · 2024

Journal of Alloys and Compounds

Advances in Fe3+-activated luminescent materials for near-infrared light sources

Fangyi Zhao, Zhen Song · 2024

Progress in Solid State Chemistry

Structural confinement toward suppressing concentration and thermal quenching for improving near-infrared luminescence of Fe3+

Fangyi Zhao, Yuhe Shao · 2023

Inorganic Chemistry Frontiers

Achieving Broadband NIR Emission in Fe3+‐Activated ALaBB′O6 (A = Ba, Sr, Ca; B–B′ = Li–Te, Mg–Sb) Phosphors via Multi‐Site Ionic Co‐Substitutions

Shikun Su, Chen Hu · 2023

Advanced Optical Materials

Metrics

46

Citations

27

References

Details

Published: Feb 28, 2023
Vol/Issue: 48(5)
Pages: 1296
License: View

Authors

Cite This Article

Gaochao Liu, Zhiguo Xia (2023). Multi-sites energy transfer in Fe3+-doped KAl11O17 phosphor toward zero thermal quenching near-infrared luminescence. Optics Letters, 48(5), 1296. https://doi.org/10.1364/ol.481641

Multi-sites energy transfer in Fe3+-doped KAl11O17 phosphor toward zero thermal quenching near-infrared luminescence

You May Also Like