Solid-state mechanochemical cross-coupling of insoluble substrates into insoluble products by removable solubilizing silyl groups: uniform synthesis of nonsubstituted linear oligothiophenes

Koji Kubota; Keisuke Kondo; Tamae Seo; Mingoo Jin; Hajime Ito

doi:10.1039/d3ra05571j

journal article Open Access Jan 01, 2023

Solid-state mechanochemical cross-coupling of insoluble substrates into insoluble products by removable solubilizing silyl groups: uniform synthesis of nonsubstituted linear oligothiophenes

Koji Kubota

Keisuke Kondo Tamae Seo Mingoo Jin

Hajime Ito

RSC Advances Vol. 13 No. 41 pp. 28652-28657 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d3ra05571j

Abstract

We developed a new solid-state mechanochemical strategy using a removable and solubilizing silyl group that enables the organic transformation of insoluble substrates into insoluble products.

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Details

Published: Jan 01, 2023
Vol/Issue: 13(41)
Pages: 28652-28657
License: View

Authors

K

Koji Kubota

Division of Applied Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo, Hokkaido, Japan; Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo, Hokkaido, Japan

K

Keisuke Kondo

Division of Applied Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo, Hokkaido, Japan

T

Tamae Seo

Division of Applied Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo, Hokkaido, Japan

M

Mingoo Jin

Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo, Hokkaido, Japan

H

Hajime Ito

Division of Applied Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo, Hokkaido, Japan; Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo, Hokkaido, Japan

Funding

Japan Society for the Promotion of Science Award: 21H01926

Ministry of Education, Culture, Sports, Science and Technology

Cite This Article

Koji Kubota, Keisuke Kondo, Tamae Seo, et al. (2023). Solid-state mechanochemical cross-coupling of insoluble substrates into insoluble products by removable solubilizing silyl groups: uniform synthesis of nonsubstituted linear oligothiophenes. RSC Advances, 13(41), 28652-28657. https://doi.org/10.1039/d3ra05571j

Solid-state mechanochemical cross-coupling of insoluble substrates into insoluble products by removable solubilizing silyl groups: uniform synthesis of nonsubstituted linear oligothiophenes

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