journal article Open Access May 17, 2019

TiO2 NPs Assembled into a Carbon Nanofiber Composite Electrode by a One-Step Electrospinning Process for Supercapacitor Applications

Polymers Vol. 11 No. 5 pp. 899 · MDPI AG
View at Publisher Save 10.3390/polym11050899
Abstract
In this study, we have synthesized titanium dioxide nanoparticles (TiO2 NPs) into carbon nanofiber (NFs) composites by a simple electrospinning method followed by subsequent thermal treatment. The resulting composite was characterized by state-of-the-art techniques and exploited as the electrode material for supercapacitor applications. The electrochemical behavior of the as-synthesized TiO2 NPs assembled into carbon nanofibers (TiO2-carbon NFs) was investigated and compared with pristine TiO2 NFs. The cyclic voltammetry and charge–discharge analysis of the composite revealed an enhancement in the performance of the composite compared to the bare TiO2 NFs. The as-obtained TiO2-carbon NF composite exhibited a specific capacitance of 106.57 F/g at a current density of 1 A/g and capacitance retention of about 84% after 2000 cycles. The results obtained from this study demonstrate that the prepared nanocomposite could be used as electrode material in a supercapacitor. Furthermore, this work provides an easy scale-up strategy to prepare highly efficient TiO2-carbon composite nanofibers.
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References
47
[1]
Pant "Carbon nanofibers wrapped with zinc oxide nano-flakes as promising electrode material for supercapacitors" J. Colloid Interface Sci. (2018) 10.1016/j.jcis.2018.03.055
[2]
Elmouwahidi "Carbon–TiO2 composites as high-performance supercapacitor electrodes: synergistic effect between carbon and metal oxide phases" J. Mater. Chem. A (2018) 10.1039/c7ta08023a
[3]
Jiang "Progress of Nanostructured Electrode Materials for Supercapacitors" Adv. Sustainable Syst. (2018) 10.1002/adsu.201700110
[4]
Nanostructured carbon–metal oxide composite electrodes for supercapacitors: a review

Mingjia Zhi, Chengcheng Xiang, Jiangtian Li et al.

Nanoscale 2013 10.1039/c2nr32040a
[5]
Ojha "Synthesis and characterization of reduced graphene oxide decorated with CeO2-doped MnO2 nanorods for supercapacitor applications" J. Colloid Interface Sci. (2017) 10.1016/j.jcis.2017.01.100
[6]
Pant "General one-pot strategy to prepare Ag–TiO2 decorated reduced graphene oxide nanocomposites for chemical and biological disinfectant" J. Alloys Compd. (2016) 10.1016/j.jallcom.2016.02.067
[7]
Yu "Recent advances in the synthesis and energy applications of TiO2-graphene nanohybrids" Sol. Energy Mater. Sol. Cells (2017) 10.1016/j.solmat.2017.07.045
[8]
Boppella "Hierarchical rutile TiO2 aggregates: A high photonic strength material for optical and optoelectronic devices" Acta Mater. (2016) 10.1016/j.actamat.2016.08.004
[9]
Pazhamalai "Blue TiO2 nanosheets as a high-performance electrode material for supercapacitors" J. Colloid Interface Sci. (2019) 10.1016/j.jcis.2018.10.031
[10]
Heng, I., Lai, C.W., Juan, J.C., Numan, A., Iqbal, J., and Teo, E.Y.L. (2018). Low-temperature synthesis of TiO2 nanocrystals for high performance electrochemical supercapacitors. Ceram. Int. 10.1016/j.ceramint.2018.11.199
[11]
Breckenridge "Electrical Properties of Titanium Dioxide Semiconductors" Phys. Rev. (1953) 10.1103/physrev.91.793
[12]
Li "Three-dimensional hierarchical graphene/TiO2 composite as high-performance electrode for supercapacitor" J. Alloys Compd. (2018) 10.1016/j.jallcom.2018.02.210
[13]
Thirugnanam "Few layer graphene wrapped mixed phase TiO2 nanofiber as a potential electrode material for high performance supercapacitor applications" Appl. Surf. Sci. (2018) 10.1016/j.apsusc.2018.02.286
[14]
Tiwari "Boosted electrochemical performance of TiO2 decorated RGO/CNT hybrid nanocomposite by UV irradiation" Vacuum (2019) 10.1016/j.vacuum.2018.11.052
[15]
Zhang "CNTs/TiO2 composites and its electrochemical properties after UV light irradiation" Prog. Nat. Sci. Mater. Int. (2013) 10.1016/j.pnsc.2013.03.002
[16]
Sun "Pseudocapacitance of Amorphous TiO2 Thin Films Anchored to Graphene and Carbon Nanotubes Using Atomic Layer Deposition" J. Phys. Chem. C (2013) 10.1021/jp4066955
[17]
"Carbon nanotube/ polypyrrole nanofibers core–shell composites decorated with titanium dioxide nanoparticles for supercapacitor electrodes" J. Power Sources (2014) 10.1016/j.jpowsour.2014.06.027
[18]
Jun "Comparative study of acid functionalization of carbon nanotube via ultrasonic and reflux mechanism" J. Environ. Chem. Eng. (2018) 10.1016/j.jece.2018.09.008
[19]
Aryal "Multi-walled carbon nanotubes/TiO2 composite nanofiber by electrospinning" Mater. Sci. Eng. C (2008) 10.1016/j.msec.2007.10.002
[20]
Pant "Immobilization of TiO2 nanofibers on reduced graphene sheets: Novel strategy in electrospinning" J. Colloid Interface Sci. (2015) 10.1016/j.jcis.2015.06.043
[21]
Ramadoss "Fabrication of reduced graphene oxide/TiO2 nanorod/reduced graphene oxide hybrid nanostructures as electrode materials for supercapacitor applications" CrystEngComm (2013) 10.1039/c3ce41517a
[22]
Selvakumar "Microwave synthesized nanostructured TiO2-activated carbon composite electrodes for supercapacitor" Appl. Surf. Sci. (2012) 10.1016/j.apsusc.2012.09.036
[23]
Pant "CdS-TiO2 NPs decorated carbonized eggshell membrane for effective removal of organic pollutants: A novel strategy to use a waste material for environmental remediation" J. Alloys Compd. (2017) 10.1016/j.jallcom.2016.12.360
[24]
Tang "Amorphous-crystalline TiO2/carbon nanofibers composite electrode by one-step electrospinning for symmetric supercapacitor" Electrochim. Acta (2016) 10.1016/j.electacta.2015.12.209
[25]
Pant "Carbon nanofibers decorated with binary semiconductor (TiO2/ZnO) nanocomposites for the effective removal of organic pollutants and the enhancement of antibacterial activities" Ceram. Int. (2013) 10.1016/j.ceramint.2013.02.041
[26]
Zhang "Recent advances in electrospun carbon nanofibers and their application in electrochemical energy storage" Prog. Mater. Sci. (2016) 10.1016/j.pmatsci.2015.08.002
[27]
Seki "Novel polyimide-based electrospun carbon nanofibers prepared using ion-beam irradiation" Polymer (2012) 10.1016/j.polymer.2012.03.026
[28]
Hussain "Hybrid Monolith of Graphene/TEMPO-Oxidized Cellulose Nanofiber as Mechanically Robust, Highly Functional, and Recyclable Adsorbent of Methylene Blue Dye" J. Nanomater. (2018) 10.1155/2018/5963982
[29]
TEMPO-oxidized cellulose nanofibers

Akira Isogai, Tsuyoshi SAITO, Hayaka Fukuzumi

Nanoscale 2011 10.1039/c0nr00583e
[30]
Jain "Activated carbons derived from coconut shells as high energy density cathode material for Li-ion capacitors" Sci. Rep. (2013) 10.1038/srep03002
[31]
Hong "Development of porous carbon nanofibers from electrospun polyvinylidene fluoride for CO2 capture" RSC Adv. (2014) 10.1039/c4ra11290c
[32]
Pant "Synthesis and photocatalytic activities of CdS/TiO2 nanoparticles supported on carbon nanofibers for high efficient adsorption and simultaneous decomposition of organic dyes" J. Colloid Interface Sci. (2014) 10.1016/j.jcis.2014.07.039
[33]
Fatema "Fabrication of carbon fibers from electrospun poly(vinyl alcohol) nanofibers" Text. Res. J. (2011) 10.1177/0040517510385175
[34]
Lignosulphonate-cellulose derived porous activated carbon for supercapacitor electrode

Zhenhuan Zhao, Shimeng Hao, Pin Hao et al.

Journal of Materials Chemistry A 2015 10.1039/c5ta02770e
[35]
Wei "3D Porous Hierarchical Microspheres of Activated Carbon from Nature through Nanotechnology for Electrochemical Double-Layer Capacitors" ACS Sustainable Chem. Eng. (2016) 10.1021/acssuschemeng.6b01227
[36]
Wang "TiO2 nanoparticle decorated carbon nanofibers for removal of organic dyes" Colloids Surf. A (2018) 10.1016/j.colsurfa.2018.04.017
[37]
Gu "Preparation and surface structures of carbon nanofibers produced from electrospun PAN precursors" New Carbon Mater. (2008) 10.1016/s1872-5805(08)60021-9
[38]
Pant "Electrospun CdS–TiO2 doped carbon nanofibers for visible-light-induced photocatalytic hydrolysis of ammonia borane" Catal. Commun. (2014) 10.1016/j.catcom.2014.03.002
[39]
Wetchakun "Influence of calcination temperature on anatase to rutile phase transformation in TiO2 nanoparticles synthesized by the modified sol–gel method" Mater. Lett. (2012) 10.1016/j.matlet.2012.05.092
[40]
Mazza "Raman spectroscopy characterization of TiO2 rutile nanocrystals" Phys. Rev. B (2007) 10.1103/physrevb.75.045416
[41]
Adhikari "Electrospinning Directly Synthesized Porous TiO2 Nanofibers Modified by Graphitic Carbon Nitride Sheets for Enhanced Photocatalytic Degradation Activity under Solar Light Irradiation" Langmuir (2016) 10.1021/acs.langmuir.6b01085
[42]
Saud "Effective photocatalytic efficacy of hydrothermally synthesized silver phosphate decorated titanium dioxide nanocomposite fibers" J. Colloid Interface Sci. (2016) 10.1016/j.jcis.2015.11.072
[43]
Gao "Chemical vapor-deposited carbon nanofibers on carbon fabric for supercapacitor electrode applications" Nanoscale Res. Lett. (2012) 10.1186/1556-276x-7-651
[44]
Pant "Fly-ash-incorporated electrospun zinc oxide nanofibers: Potential material for environmental remediation" Environ. Pollut. (2019) 10.1016/j.envpol.2018.10.122
[45]
Jiang "Bio-derived three-dimensional hierarchical carbon-graphene-TiO2 as electrode for supercapacitors" Sci. Rep. (2018) 10.1038/s41598-018-22742-7
[46]
Hsieh "Electrochemical capacitance from carbon nanotubes decorated with titanium dioxide nanoparticles in acid electrolyte" J. Phys. Chem. Solids (2009) 10.1016/j.jpcs.2009.04.012
[47]
Tolba "Synthesis of Novel Fe-doped Amorphous TiO2/C Nanofibers for Supercapacitors Applications" Int. J. Electrochem. Sci. (2015) 10.1016/s1452-3981(23)06524-0
Metrics
95
Citations
47
References
Details
Published
May 17, 2019
Vol/Issue
11(5)
Pages
899
License
View
Funding
National Research Foundation of Korea Award: 2018M3C1B5052207
Cite This Article
Bishweshwar Pant, Mira Park, Soo-Jin Park (2019). TiO2 NPs Assembled into a Carbon Nanofiber Composite Electrode by a One-Step Electrospinning Process for Supercapacitor Applications. Polymers, 11(5), 899. https://doi.org/10.3390/polym11050899
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