journal article Open Access Oct 26, 2022

Rigid Polyurethane Biofoams Filled with Chemically Compatible Fruit Peels

Polymers Vol. 14 No. 21 pp. 4526 · MDPI AG
View at Publisher Save 10.3390/polym14214526
Abstract
Banana and bergamot peels are underutilized byproducts of the essential oil and juice-processing industry. This study was designed for the development of rigid polyurethane foam (RPUF) composites using polysaccharide-rich fruit peels as fillers. These fillers were characterized for chemical properties using wet analyses. Additionally, the influences of the filler type and filler content on morphological, thermal, mechanical, hygroscopic, and colorimetric properties of the RPUF were investigated. The main results indicated that, in a comparison with the neat RPUF, the insertion of up to 15% of fillers yielded similar water uptake, apparent density, compressive strength, and color properties, as well as increases up to 115% in thermal stability and up to 80% in cell size.
Topics

No keywords indexed for this article. Browse by subject →

References
30
[1]
Kremensas "Nutmeg filler as a natural compound for the production of polyurethane composite foams with antibacterial and anti-aging properties" Polym. Test. (2020) 10.1016/j.polymertesting.2020.106479
[2]
Kirpluks "Paper waste sludge enhanced eco-efficient polyurethane foam composites: Physical-mechanical properties and microstructure" Polym. Compos. (2016)
[3]
Jonjaroen "Algal cellulose as a reinforcement in rigid polyurethane foam" Algal Res. (2020) 10.1016/j.algal.2020.102057
[4]
Mahmood "Depolymerization of lignins and their applications for the preparation of polyols and rigid polyurethane foams: A review" Renew. Sustain. Energy Rev. (2016) 10.1016/j.rser.2016.01.037
[5]
Akdogan "Improvement in physico-mechanical and structural properties of rigid polyurethane foam composites by the addition of sugar beet pulp as a reactive filler" J. Polym. Res. (2021) 10.1007/s10965-021-02445-w
[6]
Zieleniewska "Modification of flexible polyurethane foams by the addition of natural origin fillers" Polym. Degrad. Stab. (2016) 10.1016/j.polymdegradstab.2016.05.002
[7]
Petzhold "Forest-based resources as fillers in biobased polyurethane foams" J. Appl. Polym. Sci. (2018) 10.1002/app.45684
[8]
Martins "Valorization of Banana Peel Waste Used as Filler in Castor Oil Polyurethane Foam for Vegetal Oil Sorption" J. Nat. Fibers (2021)
[9]
de Luca Bossa, F., Santillo, C., Verdolotti, L., Campaner, P., Minigher, A., Boggioni, L., Losio, S., Coccia, F., Iannace, S., and Lama, G.C. (2020). Greener Nanocomposite Polyurethane Foam Based on Sustainable Polyol and Natural Fillers: Investigation of Chemico-Physical and Mechanical Properties. Materials, 13. 10.3390/ma13010211
[10]
Gangoiti "Cellulose nanocrystal reinforced acylglycerol-based polyurethane foams" Express Polym. Lett. (2020) 10.3144/expresspolymlett.2020.52
[11]
Husainie "A Comparative Study on the Mechanical Properties of Different Natural Fiber Reinforced Free-Rise Polyurethane Foam Composites" Ind. Eng. Chem. Res. (2020) 10.1021/acs.iecr.0c04006
[12]
Effects of different catalysts on the structure and properties of polyurethane/water glass grouting materials

Qian Zhang, Xiang‐Ming Hu, Ming‐Yue Wu et al.

Journal of Applied Polymer Science 2018 10.1002/app.46460
[13]
Kerche "Surface response and photodegradation performance of bio-based polyurethane-forest derivatives foam composites" Polym. Test. (2019) 10.1016/j.polymertesting.2019.106102
[14]
FAO (2021, June 04). Food and Agriculture Organization of the USA. Available online: http://www.fao.org/faostat/en/#home.
[15]
Pathak "Valorization of banana peel: A biorefinery approach" Rev. Chem. Eng. (2016) 10.1515/revce-2015-0063
[16]
Mandalari "Characterization of Flavonoids and Pectins from Bergamot (Citrus bergamia Risso) Peel, a Major Byproduct of Essential Oil Extraction" J. Agric. Food Chem. (2006) 10.1021/jf051847n
[17]
Petzhold "Thermal and Combustion Features of Rigid Polyurethane Biofoams Filled with Four Forest-Based Wastes" Polym. Compos. (2018)
[18]
(2000). Standard Test Method for Compressive Properties of Rigid Cellular Plastics. Standard No. ASTM D 1621.
[19]
(2022, October 21). ISO 2896—Rigid Cellular Plastics—Determination of Water Absorption. Available online: https://www.iso.org/standard/30408.html.
[20]
Kabenge "Characterization of Banana Peels Wastes as Potential Slow Pyrolysis Feedstock" J. Sustain. Dev. (2018) 10.5539/jsd.v11n2p14
[21]
Qu "Preparation and characterization of hydrophobic coatings on wood surfaces by a sol-gel method and post-aging heat treatment" Polym. Degrad. Stab. (2021) 10.1016/j.polymdegradstab.2020.109429
[22]
Domingos "Food and Bioproducts Processing.Polyurethane Foams from Liquefied Orange Peel Wastes" Food Bioprod. Process. (2019) 10.1016/j.fbp.2019.04.002
[23]
Oberoi "Statistical optimization of hydrolysis process for banana peels using cellulolytic and pectinolytic enzymes" Food Bioprod. Process. (2011) 10.1016/j.fbp.2011.05.002
[24]
Stanzione "Tuning of polyurethane foam mechanical and thermal properties using ball-milled cellulose" Carbohydr. Polym. (2020) 10.1016/j.carbpol.2019.115772
[25]
Kerche "Micro fibrillated cellulose reinforced bio-based rigid high-density polyurethane foams" Cellulose (2021) 10.1007/s10570-021-03801-1
[26]
Kairytė, A., Członka, S., Boris, R., and Vėjelis, S. (2021). Evaluation of the Performance of Bio-Based Rigid Polyurethane Foam with High Amounts of Sunflower Press Cake Particles. Materials, 14. 10.3390/ma14195475
[27]
Septevani "The use of cellulose nanocrystals to enhance the thermal insulation properties and sustainability of rigid polyurethane foam" Ind. Crop. Prod. (2017) 10.1016/j.indcrop.2017.05.039
[28]
Zieleniewska "Development and applicational evaluation of the rigid polyurethane foam composites with egg shell waste" Polym. Degrad. Stab. (2016) 10.1016/j.polymdegradstab.2016.02.030
[29]
Rigid bio-based wood/polyurethane foam composites expanded under confinement

Eduardo Fischer Kerche, Rafael de Avila Delucis, Cesar Liberato Petzhold et al.

Journal of Cellular Plastics 2020 10.1177/0021955x20964018
[30]
Gu "A feasibility study of polyurethane composite foam with added hardwood pulp" Ind. Crop. Prod. (2013) 10.1016/j.indcrop.2012.06.006
Related

You May Also Like

Poly Lactic-co-Glycolic Acid (PLGA) as Biodegradable Controlled Drug Delivery Carrier

Hirenkumar K. Makadia, Steven J. Siegel · 2011

3,980 citations

Chitosan: An Overview of Its Properties and Applications

Inmaculada Aranaz, Andrés R. Alcántara · 2021

1,433 citations

Thermoresponsive Polymers for Biomedical Applications

Mark A. Ward, Theoni K. Georgiou · 2011

1,048 citations